15233-47-3Relevant articles and documents
Method for one-step continuous synthesis of N-sec-octyl-N'-phenyl-p-phenylenediamine
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Paragraph 0015; 0016; 0017, (2016/10/08)
The present invention relates to a synthesis method of an anti-aging agent NN-sec-octyl-N'-phenyl-p-phenylenediamine. The method is characterized in that 2-octanone and 4-aminodiphenylamine are adopted as basic raw materials, a continuous condensation hydrogenation reaction is performed in a fixed bed in the presence of a catalyst to obtain a mixture containing N-sec-octyl-N'-phenyl-p-phenylenediamine, and a purification treatment is performed to obtain N-sec-octyl-N'-phenyl-p-phenylenediamine. According to the present invention, the method is different from the previous method using the nickel catalyst kettle type intermittent reaction, the fixed bed device is used and the copper catalyst is used to carry out the continuous hydrogenation reaction, and the method is suitable for industrial continuous production.
2-Propanol derivatives as corrosion inhibitors
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, (2008/06/13)
New composition comprises a functional fluid in contact with ferrous metal and a corrosion inhibiting amount of at least one compound of formula (I) STR1 or a derivative thereof in which R1, R2 and R3 are, independently, hydrogen, a C1 -C15 straight or branched chain alkyl residue, a C5 -C12 cycloalkyl residue, a C6 -C15 aryl residue or C7 -C12 alkaryl residue, and R4 and R5 are, independently, hydrogen, 2-hydroxyethyl or 2-hydroxypropyl with the provisos that (a) R4 and R5 are not simultaneously hydrogen, (b) when R4 and R5 are each --CH2 --CH2 --OH, R1 and R2 are not simultaneously hydrogen and R3 is not a pentyl residue and (c) that polyalkylene and phenol or polycarboxylic ester co-additives are absent; as well as salts thereof. Some of the compounds of formula I are new.
Triazole-organodithiophosphate reaction product additives for functional fluids
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, (2008/06/13)
New reaction products, useful as additives for functional fluids, are obtained by reacting, at elevated temperature, (A) a triazole having the formula IA or IB: STR1 wherein R7 is hydrogen or a C1 -C20 alkyl residue; R8 and R9 are the same or different and each is C1 -C20 alkyl, C3 -C20 alkenyl, C5 -C12 cycloalkyl, C7 -C13 aralkyl, C6 -C10 aryl or R8 and R9, together with the nitrogen atom to which they are attached, form a 5-, 6- or 7-membered heterocyclic residue or R8 and R9 is each a residue of formula: wherein X is O, S or N(R12), R12 is hydrogen or C1 -C20 alkyl, "alkylene" is a C1 -C12 alkylene residue and n is 0 or an integer from 1 to 6; R10 is hydrogen, C1 -C20 alkyl or C6 -C10 aryl or C7 -C18 alkyl phenyl; and R11 is hydrogen, C1 -C20 alkyl or a residue --CH2 NR8 R9 wherein R8 and R9 have their previous significance; with (B) an organodithiophosphate having the formula: STR2 in which R13 is a C1 -C20 alkyl or C7 -C18 alkyl phenyl or C7 -C13 aralkyl group, M is a metal ion of Group IA, IB, IIA, IIB, VB, VIB, VIIB or VIII of the Periodic System of Elements, and y is the valency of M.