152420-91-2

Basic information

• Product Name: 1-O,2-S-(2-acetyl-1-methyl-1,2-ethenediyl)-3,4,6-tri-O-benzyl-2-thio-α-D-glucopyranose
• Synonyms: 1-O,2-S-(2-acetyl-1-methyl-1,2-ethenediyl)-3,4,6-tri-O-benzyl-2-thio-α-D-glucopyranose
• CAS NO: 152420-91-2
• Molecular Weight: 546.684
• Mol File: 152420-91-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-O,2-S-(2-acetyl-1-methyl-1,2-ethenediyl)-3,4,6-tri-O-benzyl-2-thio-α-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O,2-S-(2-acetyl-1-methyl-1,2-ethenediyl)-3,4,6-tri-O-benzyl-2-thio-α-D-glucopyranose(152420-91-2)
• EPA Substance Registry System: 1-O,2-S-(2-acetyl-1-methyl-1,2-ethenediyl)-3,4,6-tri-O-benzyl-2-thio-α-D-glucopyranose(152420-91-2)

Safety Data

• Hazardous Substances Data: 152420-91-2(Hazardous Substances Data)

Upstream product

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 107552-89-6 3-thiophthalimide-2,4-pentanedione 
• 123-54-6 acetylacetone 
• 13257-81-3 4-trimethylsiloxy-3-penten-2-one 
• 13265-84-4 D-glucal 
• 100-39-0 benzyl bromide 
• 67-56-1 methanol 
• 152420-82-1 2-((E)-1-Acetyl-2-hydroxy-propenylsulfanyl)-isoindole-1,3-dione 
• 144760-54-3 2-((E)-1-Acetyl-2-hydroxy-propenylsulfanyl)-isoindole-1,3-dione 

Downstream Products

• 185836-62-8 3-[(2S,3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-(naphthalen-2-yloxy)-tetrahydro-pyran-3-ylsulfanyl]-4-methyl-pent-3-en-2-one 
• 180714-42-5 (2R,3S,4R,6R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-6-((R)-3-hexadecyloxy-2-methoxy-propoxy)-tetrahydro-pyran 
• 136174-75-9 2-naphthyl 3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 243142-15-6 (3aR,5R,5aS,8aS,8bR)-5-[(3R,4aR,6R,7R,8S,8aR)-7,8-Bis-benzyloxy-6-benzyloxymethyl-2-eth-(Z)-ylidene-3-methyl-hexahydro-4,5-dioxa-1-thia-naphthalen-3-yloxymethyl]-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran 
• 354797-84-5 fluorenyl 2-S-(1'-acetyl-2'-methylethenyl)-3,4,6-tri-O-benzyl-2-thio-β-D-glucopyranoside 
• 354797-83-4 menthyl 2-S-(1'-acetyl-2'-methylethenyl)-3,4,6-tri-O-benzyl-2-thio-β-D-glucopyranoside 
• 354797-82-3 [1-((4aR,6R,7R,8S,8aR)-7,8-Bis-benzyloxy-6-benzyloxymethyl-3-methyl-6,7,8,8a-tetrahydro-4aH-4,5-dioxa-1-thia-naphthalen-2-yl)-ethoxy]-tert-butyl-dimethyl-silane 

Relevant articles and documents

Recent advances in the synthesis of 2-deoxy-glycosides

Glycosides of 2-deoxy-sugars, monosaccharides in which the hydroxyl group at C-2 is replaced with a hydrogen atom, occur widely in natural products and therefore have been the subject of intense synthetic activity. The report summarizes recent advances in this area, with a particular focus on work published since an earlier review on the topic, in 2000 (Marzabadi, C. H.; Franck, R. W. Tetrahedron 2000, 56, 8385-8417).

Cycloaddition als Methode zur Glycosidierung

Keywords: Cycloadditionen; Glycale; Glycoside; Thione

Phthalimidesulfenyl Chloride Part 6. The First Example of an α-Oxothione Acting as Heterodiene: Synthesis of 2,3-Dihydro-1,4-Oxathiines.

α-α'-Dioxothione 3a acts as heterodiene undergoing 4 + 2 cycloaddition reactions with enol ethers with the regiospecific formation of 2,3-dihydro-1,4-oxathiines 5 in good yields.The reaction is very simple and quite general.Using this reaction the thiosug