152429-52-2

Basic information

• Product Name: 6-allyl-2,6-dimethyl-1-cyclohexene-1-carbaldehyde trimethyleneacetal
• Synonyms: 6-allyl-2,6-dimethyl-1-cyclohexene-1-carbaldehyde trimethyleneacetal
• CAS NO: 152429-52-2
• Molecular Weight: 236.354
• Mol File: 152429-52-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-allyl-2,6-dimethyl-1-cyclohexene-1-carbaldehyde trimethyleneacetal(CAS DataBase Reference)
• NIST Chemistry Reference: 6-allyl-2,6-dimethyl-1-cyclohexene-1-carbaldehyde trimethyleneacetal(152429-52-2)
• EPA Substance Registry System: 6-allyl-2,6-dimethyl-1-cyclohexene-1-carbaldehyde trimethyleneacetal(152429-52-2)

Safety Data

• Hazardous Substances Data: 152429-52-2(Hazardous Substances Data)

Upstream product

• 152429-49-7 6-allyl-2,6-dimethyl-2-cyclohexen-1-one 
• 40790-56-5 2,6-dimethyl-2-cyclohexen-1-one 
• 152429-51-1 6-allyl-2,6-dimethyl-1-cyclohexene-1-carbaldehyde 
• 504-63-2 trimethyleneglycol 

Downstream Products

• 152429-56-6 ethyl (Z)-5-<2-(1,3-dioxan-2-yl)-1,3-dimethyl-2-cyclohexenyl>-2-trimethylsilylmethyl-2-pentenoate 
• 152429-58-8 ethyl (Z)-5-(2-formyl-1,3-dimethyl-2-cyclohexenyl)-2-trimethylsilylmethyl-2-pentenoate 
• 152429-55-5 3-<2-(1,3-dioxan-2-yl)-1,3-dimethyl-2-cyclohexenyl>-propanal 
• 152429-54-4 3-<2-(1,3-dioxan-2-yl)-1,3-dimethyl-2-cyclohexenyl>-1-propanol 

Relevant articles and documents

Synthesis of a Stereoisomer of Frullanolide Utilizing the Intamolecular Cyclization of ω-Formyl-2-alkenylsilane

Synthesis of 10-epi-frullanolide (3) is reported via the intramolecular cyclization of ω-formyl-α-trimethylsilylmethyl-α,β-unsaturated ester.The cyclization precursor, ethyl (Z)-5-(2-formyl-1,3-dimethyl-2-cyclohexenyl)-2-trimethylsilylmethyl-2-pentenoate (17), was prepared from 2,6-dimethyl-2-cyclohexen-1-one through the dialdehyde monoacetal as the key intermediate.Cyclization of 17 with tetrabutylammonium fluoride produced the hydroxy ester having C(6α)-H and C(7β)-H, which was hydrolyzed, then subjected to Fujisawa's lactonization to afford 3.