152496-58-7

Basic information

• Product Name: N-benzyl,N-(2-methyl-3-oxo-cyclopent-1-enyl)-2-methoxyacetamide
• CAS NO: 152496-58-7
• Molecular Weight: 273.332
• Mol File: 152496-58-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl,N-(2-methyl-3-oxo-cyclopent-1-enyl)-2-methoxyacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl,N-(2-methyl-3-oxo-cyclopent-1-enyl)-2-methoxyacetamide(152496-58-7)
• EPA Substance Registry System: N-benzyl,N-(2-methyl-3-oxo-cyclopent-1-enyl)-2-methoxyacetamide(152496-58-7)

Safety Data

• Hazardous Substances Data: 152496-58-7(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 5870-63-3 3-hydroxy-2-methyl-2-cyclopenten-1-one 
• 38870-89-2 Methoxyacetyl chloride 
• 134622-65-4 3-(benzylamino)-2-methylcyclopent-2-en-1-one 

Relevant articles and documents

Photorearrangement of N-alkanoyl β-enaminones. Application to the synthesis of α-amino-β,γ-unsaturated acid derivatives

The irradiation of N-alkanoyll-β-enaminones lead to the formation of spiranic β-lactams which undergo C-N bond cleavage during chromatography on alumina giving cycloalkenones functionalized at position 3. This new rearrangement has been applied to the synthesis of α-amino-β,γ-unsaturated amides in one step and gives convenient yields.