1527-96-4 Usage
Description
CROTONALDEHYDE (DNPH DERIVATIVE) is a dinitrophenylhydrazone (DNPH) derivative of an aliphatic aldehyde, specifically derived from crotonaldehyde, which is found in mainstream cigarette smoke. CROTONALDEHYDE (DNPH DERIVATIVE) is known for its characteristic properties as a derivative, which can be utilized in various applications.
Uses
Used in Chemical Analysis:
CROTONALDEHYDE (DNPH DERIVATIVE) is used as a reagent for the detection and quantification of aldehydes, such as crotonaldehyde, in various samples. The application reason is its ability to form stable derivatives with aldehydes, which can be easily analyzed and identified using spectroscopic techniques.
Used in Environmental Monitoring:
In the Environmental Industry, CROTONALDEHYDE (DNPH DERIVATIVE) is used as a monitoring agent for assessing the levels of harmful aldehydes, like crotonaldehyde, in cigarette smoke and other polluted environments. The application reason is its high specificity and sensitivity in detecting and quantifying these toxic compounds, which can help in evaluating the health risks associated with exposure to such pollutants.
Used in Pharmaceutical Research:
CROTONALDEHYDE (DNPH DERIVATIVE) is used as a research tool in the pharmaceutical industry for studying the effects of aldehydes on biological systems and their potential role in various diseases. The application reason is its ability to provide valuable insights into the molecular mechanisms underlying the toxic effects of aldehydes, which can aid in the development of new therapeutic strategies and drug candidates.
Used in Dyes and Metabolites:
CROTONALDEHYDE (DNPH DERIVATIVE) is also used in the development and synthesis of dyes and metabolites, taking advantage of its unique chemical properties as a DNPH derivative. The application reason is its potential to create novel compounds with specific characteristics, which can find use in various industrial and scientific applications.
Check Digit Verification of cas no
The CAS Registry Mumber 1527-96-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,2 and 7 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1527-96:
(6*1)+(5*5)+(4*2)+(3*7)+(2*9)+(1*6)=84
84 % 10 = 4
So 1527-96-4 is a valid CAS Registry Number.
InChI:InChI=1/C10H10N4O4/c1-2-3-6-11-12-9-5-4-8(13(15)16)7-10(9)14(17)18/h2-7,12H,1H3/b3-2+,11-6+
1527-96-4Relevant articles and documents
Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway
Khandelwal, Chandra Lata,Meena, Anita,Sailani, Riya,Sharma, Priyamvada
, p. 950 - 970 (2020/09/18)
The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N -chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities such as activation energy and activation entropy are evaluated in acidic as well as in catalysed alkaline medium. An anticipated reaction mechanism has been suggested.
Cyclic α-acetoxynitrosamines: Mechanisms of decomposition and stability of α-hydroxynitrosamine and nitrosiminium ion reactive intermediates
Chahoua, Latifa,Cai, Hongliang,Fishbein, James C.
, p. 5161 - 5169 (2007/10/03)
A study of the kinetics and mechanism of the decay of α-acetoxy-N- nitrosopyrrolidine and α-acetoxy-N-nitrosopiperidine are reported. The compounds differ in reactivity by more than 2 orders of magnitude at physiological pH. On the basis of thermodynamic
AUTOOXIDATION OF ACETYLENES AND THEIR DERIVATIVES. XXV. 1-PHENYL-4-PENTEN-1-YN-3-0L AND 1-PHENYL-4-HEXEN-1-YN-3-OL
Stepin, S. G.,Tishchenko, I. G.
, p. 1771 - 1774 (2007/10/02)
During the autooxidation of secondary enynyl alcohols attack by oxygen takes place at the C-H bonds at the α position to the triple and double bonds and the hydroxyl group.The initially formed unstable hydroxyhydroperoxides dissociate under the oxidation conditions into the corresponding enynyl ketones, acetylenic keto epoxydes, and products from degradation of the carbon skeleton.