1529-78-8 Usage
Description
(2-methoxy-2-oxoethyl)(triphenyl)-lambda~5~-arsanyl is a complex organic compound that features a triphenylarsine group bonded to a (2-methoxy-2-oxoethyl) group. This molecule contains arsenic in the +3 oxidation state, which is known for its potential toxicity. The triphenylarsine segment is composed of three phenyl rings attached to an arsenic atom, while the (2-methoxy-2-oxoethyl) group includes a methoxy and a carbonyl moiety. Due to its chemical structure, this compound may have a range of applications in the field of chemistry, although its use must be approached with caution due to its toxic nature and possible environmental effects.
Uses
Used in Chemical Research:
(2-methoxy-2-oxoethyl)(triphenyl)-lambda~5~-arsanyl is used as a research compound for studying the properties and reactions of organoarsenic compounds. Its unique structure allows chemists to explore its reactivity, stability, and potential applications in various chemical processes.
Used in the Synthesis of Complex Molecules:
In the field of organic synthesis, (2-methoxy-2-oxoethyl)(triphenyl)-lambda~5~-arsanyl may serve as a building block or intermediate in the creation of more complex molecules. Its distinct functional groups can be utilized in a variety of chemical reactions to form new compounds with specific properties.
Used in Analytical Chemistry:
(2-methoxy-2-oxoethyl)(triphenyl)-lambda~5~-arsanyl could be employed as a reagent or a standard in analytical chemistry for the detection, identification, or quantification of certain substances. Its distinct chemical characteristics may make it useful in developing new analytical methods or improving existing ones.
Used in Pharmaceutical Development:
Although its toxicity must be carefully managed, (2-methoxy-2-oxoethyl)(triphenyl)-lambda~5~-arsanyl may have potential in the development of pharmaceuticals. Its unique structure could be leveraged to design new drugs or drug candidates, particularly in areas where organoarsenic compounds have shown biological activity.
Used in Material Science:
In material science, (2-methoxy-2-oxoethyl)(triphenyl)-lambda~5~-arsanyl might be investigated for its potential to contribute to the development of new materials with specific properties, such as semiconductors, catalysts, or sensors, where organoarsenic compounds could play a role.
Check Digit Verification of cas no
The CAS Registry Mumber 1529-78-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,2 and 9 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1529-78:
(6*1)+(5*5)+(4*2)+(3*9)+(2*7)+(1*8)=88
88 % 10 = 8
So 1529-78-8 is a valid CAS Registry Number.
1529-78-8Relevant articles and documents
Synthesis of olefins via a Wittig reaction mediated by triphenylarsine
Li, Lun,Stimac, Jared C.,Geary, Laina M.
supporting information, p. 1379 - 1381 (2017/03/17)
An arsine-mediated Wittig reaction for the synthesis of olefins is described. After heating triphenylarsine in the presence of an activated alkyl bromide for 30?min, the resulting arsonium salt condensed with aldehydes in as little as 5?min at room temperature, yielding the olefins in high yields. Aromatic, heteroaromatic, and alkyl aldehydes were all suitable substrates for this process.
The reaction of partially protected aldoses with stabilized arsonium ylides: Synthesis of E acyclic unsaturated derivatives and C-glycosyl derivatives
Lievre, Catherine,Frechou, Catherine,Demailly, Gilles
, p. 1 - 15 (2007/10/03)
The reaction of partially protected aldoses with (carbomethoxymethyl)triphenylarsonium bromide and zinc in toluene gave E α,β-unsaturated acyclic esters. When intramolecular transesterification occurred, bicyclic 1,4-lactone derivatives were formed concurrently. Otherwise, using these non alcaline conditions, olefination did not favour the formation of C-glycosyl derivatives. On the other hand, when the reaction was performed with (carbomethoxymethylene)triphenylarsorane in toluene, followed by the addition of n-butyllithium, bicyclic derivatives were obtained rapidly in good yields. Moreover, when cyanomethyltriphenylarsonium bromide was used in place of (carbomethoxymethyl)triphenylarsonium bromide, the corresponding E aldooctenonitriles were produced in satisfactory yields.
