1530-34-3 Usage
Description
(3,3-DIMETHYLALLYL)TRIPHENYLPHOSPHONIUM BROMIDE, also known as (3-Methyl-2-butenyl)triphenyl-phosphonium Bromide with the CAS number 1530-34-3, is an off-white solid compound that is primarily utilized in the field of organic synthesis. It is a phosphonium salt with a unique structure that contributes to its reactivity and application in various chemical reactions.
Uses
Used in Organic Synthesis:
(3,3-DIMETHYLALLYL)TRIPHENYLPHOSPHONIUM BROMIDE is used as a reagent in the field of organic synthesis for its ability to participate in various chemical reactions, such as substitution, addition, and elimination reactions. Its unique structure allows it to act as a versatile building block for the synthesis of complex organic molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (3,3-DIMETHYLALLYL)TRIPHENYLPHOSPHONIUM BROMIDE is used as an intermediate in the synthesis of various pharmaceutical compounds. Its reactivity and stability make it a valuable component in the development of new drugs and therapeutic agents.
Used in Chemical Research:
(3,3-DIMETHYLALLYL)TRIPHENYLPHOSPHONIUM BROMIDE is also used as a research tool in chemical laboratories. Its unique properties and reactivity make it an interesting subject for studying various aspects of chemistry, such as reaction mechanisms, stereochemistry, and the development of new synthetic methods.
Used in Material Science:
In the field of material science, (3,3-DIMETHYLALLYL)TRIPHENYLPHOSPHONIUM BROMIDE can be used as a component in the development of new materials with specific properties, such as conductivity, magnetism, or optical properties. Its unique structure and reactivity can contribute to the creation of novel materials with potential applications in various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 1530-34-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,3 and 0 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1530-34:
(6*1)+(5*5)+(4*3)+(3*0)+(2*3)+(1*4)=53
53 % 10 = 3
So 1530-34-3 is a valid CAS Registry Number.
InChI:InChI=1/C23H24P.BrH/c1-20(2)18-19-24(21-12-6-3-7-13-21,22-14-8-4-9-15-22)23-16-10-5-11-17-23;/h3-18H,19H2,1-2H3;1H/q+1;/p-1
1530-34-3Relevant articles and documents
Novel methodology for the preparation of five-, seven-, and nine-membered fused rings on C60
Hatzimarinaki, Maria,Orfanopoulos, Michael
, p. 1775 - 1778 (2006)
The photocycloaddition of dienyl cyclopropanes to C60 gives a new synthetic approach to yield stereospecifically five-, seven-, and nine-membered [60]fullerene adducts. Our results suggest the formation of a biradical intermediate between the dienyl substrate and C60. An electron transfer between the triplet excited state of C60 and the dienyl substrate precedes the formation of the intermediate.
Photocycloaddition of biscyclopropyl alkenes to C60: An unprecedented approach toward cis-1 tricyclic-fused fullerenes
Tzirakis, Manolis D.,Alberti, Mariza N.,Orfanopoulos, Michael
supporting information; experimental part, p. 3364 - 3367 (2011/09/12)
A novel, simple, and entirely regioselective tandem cycloaddition of biscyclopropyl-substituted alkenes to [60]fullerene has been revealed. This reaction affords cis-1 tricyclic-fused organofullerenes bearing the hitherto elusive 5-4-5 fused tricyclic ring system.
Concerning the reactivity of ptad with isomeric dienes: The mechanism of the Diels-Alder cycloaddition
Alberti, Mariza N.,Orfanopoulos, Michael
supporting information; experimental part, p. 1659 - 1662 (2009/09/07)
Cyclopropyl substituted dienes are employed as mechanistic probes in the triazolinedione Diels-Alder (DA) reaction. In aprotic and protic solvents, apart from the DA adducts that bear an intact cyclopropyl group, complicated and rearranged products are also obtained. These results provide solid evidence for the involvement of an open intermediate with a lifetime greater than 2 x 10 -12 s.
