153034-24-3

Basic information

• Product Name: 3,5-di-tert-butyl-2-(propen-3-yloxy)benzaldehyde
• Synonyms: 3,5-di-tert-butyl-2-(propen-3-yloxy)benzaldehyde
• CAS NO: 153034-24-3
• Molecular Weight: 274.403
• Mol File: 153034-24-3.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 3,5-di-tert-butyl-2-(propen-3-yloxy)benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-di-tert-butyl-2-(propen-3-yloxy)benzaldehyde(153034-24-3)
• EPA Substance Registry System: 3,5-di-tert-butyl-2-(propen-3-yloxy)benzaldehyde(153034-24-3)

Safety Data

• Hazardous Substances Data: 153034-24-3(Hazardous Substances Data)

Upstream product

• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 106-95-6 allyl bromide 

Downstream Products

• 954383-41-6 4,6-di-tert-butyl-2-(1-tert-butyldimethylsilyloxy-3-phenyl-2-propynyl)-(2-propenyloxy)benzene 
• 954383-40-5 4,6-di-tert-butyl-2-(1-tert-butyldimethylsilyloxy-3-trimethylsilyl-2-propynyl)-(2-propenyloxy)benzene 
• 954383-28-9 4,6-di-tert-butyl-2-(1-hydroxy-3-trimethylsilyl-2-propynyl)-(2-propenyloxy) benzene 
• 359011-24-8 2,4-di-tert-butyl-6-ethynyl-(2-propenyloxy)benzene 
• 1415717-34-8 2-(3,5-di-tert-butyl-2-(allyloxy)phenyl)furan 
• 1328942-38-6 2-((benzoimidazol-2-yl)methyl)-4,6-di-tert-butylphenol 
• 1328942-36-4 2-(2-(allyloxy)-3,5-di-tert-butylbenzyl)-1H-benzoimidazole 
• 1328942-35-3 2-(allyloxy)-1,5-di-tert-butyl-3-(2,2-dibromovinyl)-benzene 
• 153034-49-2 C₂₃H₃₁NO₂ 
• 153034-35-6 2-allyloxy-3,5-di-t-butylbenzyl chloride 
• 149244-07-5 2-allyloxy-3,5-di-t-butylbenzyl azide 
• 954383-39-2 4,6-di-tert-butyl-2-(1-tert-butyldimethylsilyloxy-2-propynyl)-(2-propenyloxy)benzene 

Relevant articles and documents

Catalyst-free synthesis of diversely substituted 6H-benzo[c]chromenes and 6H-benzo[c]chromen-6-ones in aqueous media under MWI

In this paper, a catalyst-free synthesis of diversely substituted 6H-benzo[c]chromenes and 6H-benzo[c]chromen-8-ols via cascade reactions of 2-(2-(allyloxy)phenyl)furan and 2-(2-(prop-2-ynyloxy)phenyl)furan, featured with intramolecular Diels-Alder reactions of furan with unactivated alkene/alkyne in aqueous media under MWI, was developed. In addition, an environmentally friendly oxidation of 6H-benzo[c]chromenes into the corresponding benzo[c]chromen-6-ones using aqueous H2O2 as an oxidant, in the absence of any activator/catalyst, was also revealed.

Metal-free synthesis of phosphinoylchroman-4-ones via a radical phosphinoylation–cyclization cascade mediated by K2S2O8

A variety of chroman-4-ones bearing phosphine oxide motifs were conveniently synthesized from readily available diphenylphosphine oxides and alkenyl aldehydes via a metal-free tandem phosphinoylation/cyclization protocol. The reaction utilizes K2S2O8 as oxidant and proceeds in DMSO/H2O at environmentally benign conditions with a broad substrate scope and afforded the title compounds in moderate yields.

Silaborative Carbocyclizations of 1,7-Enynes. Diastereoselective Preparation of Chromane Derivatives

Palladium(0)-catalyzed carbocyclization of 1,7-enynes mediated by (chlorodimethylsilyl)pinacolborane proceeds with 1,8-addition of the silicon and boron functions to give functionalized cyclohexane derivatives with boron attached to the exocyclic olefin. A variety of chromane dervatives are accessible by this method. In contrast to the analogous reactions with 1,6-enynes, the configuration of the newly formed stereogenic center is controlled by a stereogenic center present in the substrate.