153123-10-5

Basic information

• Product Name: 1-Octen-3-ol, 2-[(S)-(4-methylphenyl)sulfinyl]-1-(trimethylsilyl)-, (1E,3R)-
• CAS NO: 153123-10-5
• Molecular Formula: C18H30O2SSi
• Molecular Weight: 338.587
• Mol File: 153123-10-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Octen-3-ol, 2-[(S)-(4-methylphenyl)sulfinyl]-1-(trimethylsilyl)-, (1E,3R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Octen-3-ol, 2-[(S)-(4-methylphenyl)sulfinyl]-1-(trimethylsilyl)-, (1E,3R)-(153123-10-5)
• EPA Substance Registry System: 1-Octen-3-ol, 2-[(S)-(4-methylphenyl)sulfinyl]-1-(trimethylsilyl)-, (1E,3R)-(153123-10-5)

Safety Data

• Hazardous Substances Data: 153123-10-5(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 401614-03-7 1-phenylseleno-1-[(S)-p-tolylsulfinyl]-2-(trimethylsilyl)ethane 
• 153123-09-2 (R_S)-p-Tolyl β-(trimethylsilyl)ethyl sulfoxide 
• 66-25-1 hexanal 
• 153123-03-6 (E)-1-[(R)-p-tolylsulfinyl]-2-(trimethylsilyl)ethylene 

Downstream Products

• 32556-70-0 (R)-1-octyn-3-ol 

Relevant articles and documents

Preparation of optically pure propargylic and allylic alcohols from 2-(trimethylsilyl)vinyl sulfoxides as a chiral ethynyl anion synthon: Computational studies on elimination reaction of 2-(trimethylsilyl)vinyl sulfoxides

The reaction of the (α-carbanion derived from (trimethylsilyl)vinyl sulfoxides with aldehydes afforded a diastereomeric mixture of the products. Each diastereomer was subjected to specific elimination reactions to give optically pure propargylic, trimethylsilylated propargylic, and allylic alcohols. Acceleration of the sulfenic acid-elimination from the β-silylvinyl sulfoxide was demonstrated by the ab initio calculation to be ascribed mainly to the β-effect of the silyl group.