153277-56-6

Basic information

• Product Name: C₁₃H₂₅NOSSi₂
• CAS NO: 153277-56-6
• Molecular Weight: 299.585
• Mol File: 153277-56-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₂₅NOSSi₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₂₅NOSSi₂(153277-56-6)
• EPA Substance Registry System: C₁₃H₂₅NOSSi₂(153277-56-6)

Safety Data

• Hazardous Substances Data: 153277-56-6(Hazardous Substances Data)

Upstream product

• 50444-99-0 (1R,2S,5R)-menthyl-(S)-p-toluenesulfinate 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 188447-82-7 (S)-(+)-N-(crotonylidene)-p-toluenesulfinamide 
• 188447-84-9 (S)-N-(butylidene)-4-methylbenzenesulfinamide 
• 220273-37-0 (S,S)-N,N'-bis-(p-toluenesulfinyl)isophthaldimine 
• 220273-43-8 C₂₆H₂₂N₂O₂S₂ 
• 220273-39-2 C₂₂H₂₀N₂O₂S₂ 
• 188447-91-8 (S)-p-toluenesulfinimide 
• 220273-50-7 (R)-3-{6-[(R)-2-Methoxycarbonyl-1-((S)-toluene-4-sulfinylamino)-ethyl]-naphthalen-2-yl}-3-((S)-toluene-4-sulfinylamino)-propionic acid methyl ester 
• 220273-62-1 (S)-3-{6-[(R)-2-Methoxycarbonyl-1-((S)-toluene-4-sulfinylamino)-ethyl]-naphthalen-2-yl}-3-((S)-toluene-4-sulfinylamino)-propionic acid methyl ester 
• 220273-47-2 (R)-3-{4-[(R)-2-Methoxycarbonyl-1-((S)-toluene-4-sulfinylamino)-ethyl]-phenyl}-3-((S)-toluene-4-sulfinylamino)-propionic acid methyl ester 
• 220273-60-9 (S)-3-{4-[(R)-2-Methoxycarbonyl-1-((S)-toluene-4-sulfinylamino)-ethyl]-phenyl}-3-((S)-toluene-4-sulfinylamino)-propionic acid methyl ester 
• 220273-45-0 (R)-3-{3-[(R)-2-Methoxycarbonyl-1-((S)-toluene-4-sulfinylamino)-ethyl]-phenyl}-3-((S)-toluene-4-sulfinylamino)-propionic acid methyl ester 
• 220273-59-6 (S)-3-{3-[(R)-2-Methoxycarbonyl-1-((S)-toluene-4-sulfinylamino)-ethyl]-phenyl}-3-((S)-toluene-4-sulfinylamino)-propionic acid methyl ester 

Relevant articles and documents

Synthesis of enantiopure sulfonimidamides and elucidation of their absolute configuration by comparison of measured and calculated CD spectra and X-ray crystal structure determination

Straightforward syntheses of enantiopure N-benzoyl- and N-tert-butyloxycarbonyl-protected sulfonimidamides, which can be used as building blocks in newly designed catalysts, are presented. Key synthetic step is a dynamic resolution of a racemic sulfinic acid sodium salt. All subsequent transformations proceed stereospecifically. The absolute configurations at the sulfur atoms of both sulfonimidamides were determined by comparison of measured and calculated CD spectra. An X-ray crystal structure determination of a sulfonimidoylguanidine derivative confirmed this result.