1533-89-7

Basic information

• Product Name: cis-1-methyl-2-vinylcyclohexane
• CAS NO: 1533-89-7
• Molecular Weight: 124.226
• Mol File: 1533-89-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-1-methyl-2-vinylcyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1-methyl-2-vinylcyclohexane(1533-89-7)
• EPA Substance Registry System: cis-1-methyl-2-vinylcyclohexane(1533-89-7)

Safety Data

• Hazardous Substances Data: 1533-89-7(Hazardous Substances Data)

Upstream product

• 20993-80-0 1-(2-methylcyclohexyl)ethanol 
• 13076-15-8 trans-2-methylcyclohexanecarbaldehyde 
• 68659-61-0 methyltriphenylphosphorane 
• 76200-10-7 exo-7-chloromethyl-1-methylbicyclo<4.1.0>heptane 
• 3937-45-9 cis-1-hydroxymethyl-2-methylcyclohexane 
• 106737-78-4 dimethyl-[2-(2-methyl-cyclohexyl)-ethyl]-amine 

Downstream Products

• 7076-91-7 (+-)-cis-2-methyl-cyclohexanecarboxylic acid 
• 15177-62-5 trans-2-methylcyclohexanecarboxylic acid 

Relevant articles and documents

Ring-opening of Some Radicals containing the Cyclopropylmethyl System

Mono- and bi-cyclic radicals containing the cyclopropylmethyl system are readily generated by interaction of the appropriate halides with triphenyl- or tributyl-stannane.Each radical studied underwent ring-opening by fission of the more substituted βγ-bond.In the case of the secondary radical (12b) the new double bond was formed preferentially in the trans-configuration.Rate constants, which cannot be determined with high accuracy by this method, lie in the range 1E7-3E8 s-1 at 25 deg C.When generated by the flow method in the e.s.r. cavity α-hydroxycyclopropylmethyl radicals undergo β-fission followed by 1,5-hydrogen atom t ransfer to afford enoxyl radicals.The latter reaction occurs more slowly in water than in non-polar solvents.The rigid hydroxynortricyclyl (43) undergoes preferential fission of the less substituted βγ-bond, possibly because of the dipolar nature of the transition state.