153623-44-0

Basic information

• Product Name: (2-allyloxyphenyl)acetic acid methyl ester
• Synonyms: (2-allyloxyphenyl)acetic acid methyl ester
• CAS NO: 153623-44-0
• Molecular Weight: 206.241
• Mol File: 153623-44-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2-allyloxyphenyl)acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2-allyloxyphenyl)acetic acid methyl ester(153623-44-0)
• EPA Substance Registry System: (2-allyloxyphenyl)acetic acid methyl ester(153623-44-0)

Safety Data

• Hazardous Substances Data: 153623-44-0(Hazardous Substances Data)

Upstream product

• 22446-37-3 methyl (2-hydroxyphenyl)acetate 
• 106-95-6 allyl bromide 
• 614-75-5 2-Hydroxyphenylacetic acid 
• 67-56-1 methanol 
• 1620143-59-0 ethyl 2,2,2-trichloro-1-(2-allyloxyphenyl)ethyl carbonate 
• 90-02-8 salicylaldehyde 
• 28752-82-1 2-(allyloxy)benzaldehyde 

Downstream Products

• 99558-25-5 2-(2-(allyloxy)phenyl)acetic acid 
• 360578-36-5 2-(2-allyloxy-phenyl)-pent-4-ynoic acid methyl ester 
• 153623-48-4 2-<2-(Allyloxy)phenyl>propanol 
• 128402-44-8 (S)-1-[(E)-2-(2-Allyloxy-phenyl)-propenyl]-2-[(diphenylphosphanyl)-methyl]-pyrrolidine 
• 128402-38-0 (S)-1-[(E)-2-(2-Allyloxy-phenyl)-propenyl]-pyrrolidine-2-carboxylic acid ethyl ester 
• 128402-37-9 2-<2-(Allyloxy)phenyl>propanal 
• 383422-26-2 Benzoic acid (2R,3R,4S,5R,6S)-2-{(2S,4aR,6R,7R,8S,8aS)-7-[2-(2-allyloxy-phenyl)-acetoxy]-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxymethyl}-3,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-4-yl ester 
• 383422-35-3 Benzoic acid (2R,4aR,6S,7R,8S,8aR)-8-{(2S,3R,4S,5R,6R)-3-[2-(2-allyloxy-phenyl)-acetoxy]-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy}-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 383422-31-9 4-Oxo-pentanoic acid (2R,3R,4S,5R,6S)-4-acetoxy-2-{(2S,4aR,6R,7R,8S,8aS)-7-[2-(2-allyloxy-phenyl)-acetoxy]-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxymethyl}-5-benzyloxy-6-methoxy-tetrahydro-pyran-3-yl ester 
• 383422-28-4 (2-Allyloxy-phenyl)-acetic acid (2S,4aR,6R,7R,8S,8aS)-6-((2R,3R,4S,5R,6S)-4-acetoxy-3,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 383422-33-1 (2-Allyloxy-phenyl)-acetic acid (2S,4aR,6R,7R,8S,8aS)-6-((2R,3R,4S,5R,6S)-4-acetoxy-5-benzyloxy-3-hydroxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 383422-23-9 (2-Allyloxy-phenyl)-acetic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-ethylsulfanyl-tetrahydro-pyran-3-yl ester 
• 383422-21-7 (2-Allyloxy-phenyl)-acetic acid (2R,3R,4S,5S,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethyl ester 
• 383422-22-8 (2-Allyloxy-phenyl)-acetic acid (2S,4aR,6S,7R,8S,8aS)-8-benzyloxy-6-ethylsulfanyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 

Relevant articles and documents

Metal-Free Tandem Rearrangement/Lactonization: Access to 3,3-Disubstituted Benzofuran-2-(3H)-ones

A novel metal-free synthesis of 3,3-disubstituted benzofuran-2-(3H)-ones through reacting α-aryl-α-diazoacetates with triarylboranes is presented. Initially, triarylboranes were successfully investigated in α-arylations of α-diazoacetates, however in the presence of a heteroatom in the ortho position, the boron enolate intermediate undergoes an intramolecular rearrangement to form a quaternary center. The intermediate cyclizes to afford valuable 3,3-disubstituted benzofuranones in good yields.

The 2-(allyloxy) phenyl acetyl ester as a new relay protecting group for oligosaccharide synthesis

The 2-(allyloxy) phenyl acetyl group can be removed by a relay approach using Pd(PPh3)4 in combination with proton sponge, conditions that do not affect acetyl, benzoyl and levulinoyl esters. On the other hand, the acetyl and levulin