153710-12-4Relevant articles and documents
Modified Cinchona Alkaloid Ligands: Improved Selectivities in the Osmium Tetroxide Catalyzed Asymmetric Dihydroxylation (AD) of Terminal Olefins
Arrington, Mark P.,Bennani, Youssef L.,Goebel, Thomas,Walsh, Patrick,Zhao, Shu-Hai,Sharpless, K. Barry
, p. 7375 - 7378 (1993)
Modification on the quinuclidine and quinoline moieties of the bis cichona-alkaloid phthalazine ligands resulted in improved enantioselectivities in the osmium tetroxide catalyzed dihydroxylation of olefins.For the first time 1-decene, a common model for terminal aliphatic olefins, afforded enantioselectivities of over ninety percent.