153729-83-0

Basic information

• Product Name: (S)-3-benzoyl-4-phenylmethyl-2-oxazolidinone
• Synonyms: (S)-3-benzoyl-4-phenylmethyl-2-oxazolidinone
• CAS NO: 153729-83-0
• Molecular Weight: 281.311
• Mol File: 153729-83-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-3-benzoyl-4-phenylmethyl-2-oxazolidinone(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-benzoyl-4-phenylmethyl-2-oxazolidinone(153729-83-0)
• EPA Substance Registry System: (S)-3-benzoyl-4-phenylmethyl-2-oxazolidinone(153729-83-0)

Safety Data

• Hazardous Substances Data: 153729-83-0(Hazardous Substances Data)

Upstream product

• 50978-45-5 3-oxobenzo[d]isothiazole-2(3H)-carbaldehyde 1,1-dioxide 
• 455-32-3 benzoyl fluoride 
• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 98-88-4 benzoyl chloride 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 1019107-77-7 C₁₆H₁₆INO 
• 1019107-75-5 (S)-4-phenylmethyl-3-(phenylthioxomethyl)-2-oxazolidinone 
• 63327-99-1 (S)-4,5-dihydro-2-phenyl-4-(phenylmethyl)oxazole 
• 3532-25-0 N-benzyloxy benzamide 
• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 120-51-4 benzoic acid benzyl ester 

Relevant articles and documents

Synthesis of Chiral Selenazolines from N-Acyloxazolidinones via a Selenative Rearrangement of Chiral Cyclic Skeletons

A synthetic route to chiral selenazolines from readily available N-acyloxazolidinones via a selenative rearrangement of a chiral cyclic skeleton is reported. The reaction proceeds in the presence of elemental selenium, a hydrochlorosilane, and an amine. A

Decarboxylative isomerization of N-Acyl-2-oxazolidinones to 2-oxazolines

(Chemical Equation Presented) N-Acyl-2-oxazolidinones are ring-opened by lithium iodide and decarboxylated in the presence of a mild proton source. Further reaction with an amine base provides 2-oxazolines. The transformation is general for oxazolidinones unsubstituted in the 5 position and occurs under mild conditions (25-50°C). These results complement the existing methods for this transformation by allowing lower temperatures and/or avoiding metal catalysts.