15377-81-8Relevant articles and documents
Chlorine dioxide reduction by aqueous iron(II) through outer-sphere and inner-sphere electron-transfer pathways
Wang, Lu,Odeh, Ihab N.,Margerum, Dale W.
, p. 7545 - 7551 (2008/10/09)
The reduction of ClO2 to ClO2- by aqueous iron(II) in 0.5 M HClO4 proceeds by both outer-sphere (86%) and inner-sphere (14%) electron-transfer pathways. The second-order rate constant for the outer-sphere reacti
Fe(H2O)6.
Guarr,Buhks,McLendon
, p. 3763 - 3767 (2007/10/02)
The deuterium isotope effect on the thermodynamic driving force is discussed. Theory correctly predicts a decrease in the kinetic isotope effect as the reaction driving force increases. The observed isotope effect for replacement of H//2O by D//2O is significantly larger than predicted even after correcting for the solvent dependence of the reaction driving force.