15384-61-9

Basic information

• Product Name: methyl 4,6-O-benzylidene-3-deoxy-3-N-dimethylamino-α-D-glucopyranoside
• CAS NO: 15384-61-9
• Molecular Weight: 309.362
• Mol File: 15384-61-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-3-deoxy-3-N-dimethylamino-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-3-deoxy-3-N-dimethylamino-α-D-glucopyranoside(15384-61-9)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-3-deoxy-3-N-dimethylamino-α-D-glucopyranoside(15384-61-9)

Safety Data

• Hazardous Substances Data: 15384-61-9(Hazardous Substances Data)

Upstream product

• 124-40-3 dimethyl amine 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside 

Downstream Products

• 144901-24-6 methyl 4,6-O-benzylidene-3-deoxy-3-N-dimethylamino-α-D-glucopyranoside N-oxide 

Relevant articles and documents

CYCLOADDITION OF CHIRAL AZOMETHINE YLIDES FROM AMINOSUGAR N-OXIDES. ENANTIOSELECTIVE SYNTHESIS OF 3,4-DISUBSTITUTED PYRROLIDINES

The base deprotonation method, applied to amino-sugar N-oxides prepared from methyl 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranoside (8) and methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside (9), allows the easy generation of complex and very reactive sugar azomethine ylides.Fair yields of the major diastereomeric pyrrolidines resulting from cycloaddition to stilbene are thus obtained with good asymmetric induction.The easy elimination of the chiral appendage as starting epoxides gives access to the enantiomerically enriched 3,4-diphenylpyrrolidines.