153865-35-1

Basic information

• Product Name: Benzenamine, 3-chloro-4-methoxy-N-(1-methylethylidene)-
• CAS NO: 153865-35-1
• Molecular Weight: 197.664
• Mol File: 153865-35-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, 3-chloro-4-methoxy-N-(1-methylethylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 3-chloro-4-methoxy-N-(1-methylethylidene)-(153865-35-1)
• EPA Substance Registry System: Benzenamine, 3-chloro-4-methoxy-N-(1-methylethylidene)-(153865-35-1)

Safety Data

• Hazardous Substances Data: 153865-35-1(Hazardous Substances Data)

Upstream product

• 67-64-1 acetone 
• 5345-54-0 3-chloro-4-methoxyaniline 

Downstream Products

• 17897-50-6 4-methoxy-2-methylindole 
• 1076-74-0 5-methoxy-2-methyl-1H-indole 

Relevant articles and documents

Aggregative activation and heterocyclic chemistry I complex bases promoted arynic cyclisation of imines or enaminoketones; regiochemical synthesis of indoles

The complex base NaNH2-t-BuONa allowed expeditious syntheses of indoles by arynic cyclisation of imines or enaminoketones prepared from halogeno anilines and carbonyl derivatives. Unstable imines may be used without purification, complex bases being unsensitive to impurities. It is showed that this kind of reaction may be applied to mixture of substrates suitably halogenated on the benzene ring. Formation of three components aggregates is proposed to explain a number of observations.