154097-67-3

Basic information

• Product Name: (1S,2S,3S,4S)-5-bromo-5-cyclohexene-1,2,3,4-tetraol
• Synonyms: (1S,2S,3S,4S)-5-bromo-5-cyclohexene-1,2,3,4-tetraol
• CAS NO: 154097-67-3
• Molecular Weight: 225.039
• Mol File: 154097-67-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (1S,2S,3S,4S)-5-bromo-5-cyclohexene-1,2,3,4-tetraol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,3S,4S)-5-bromo-5-cyclohexene-1,2,3,4-tetraol(154097-67-3)
• EPA Substance Registry System: (1S,2S,3S,4S)-5-bromo-5-cyclohexene-1,2,3,4-tetraol(154097-67-3)

Safety Data

• Hazardous Substances Data: 154097-67-3(Hazardous Substances Data)

Upstream product

• 154097-68-4 (1S,2S,3S,4S)-5-bromo-1,2:3,4-di-O-isopropylidenecyclohex-5-ene-1,2,3,4-tetraol 
• 67451-62-1 cis-(1S,2S)-1,2-dihydroxy-3-bromocyclohexa-3,5-diene 

Relevant articles and documents

Concise chemoenzymatic synthesis of epi-inositol

epi-Inositol was synthesized in six steps in 40% overall yield from a bacterial bromobenzene metabolite. The chemoenzymatic route involved toluene dioxygenase oxidation, substrate-directed catalytic osmylation, m-CPBA epoxidation, radical debromination, and Amberlite-catalized hydrolysis. The route described is amenable to scaleup and could allow access to cis-inositol, and deoxy derivatives of epi-inositol.

Enantiopure arene dioxides: Chemoenzymatic synthesis and application in the production of trans-3,4-dihydrodiols

Enantiopure syn- and anti-arene dioxides are synthesised from cis-dihydrodiol metabolites; anti-benzene dioxides are reduced to enantiopure trans-3,4-dihydrodiols while synbenzene dioxides racemise thermally via 1,4-dioxocins.

Synthesis of Coduritol D Derivatives from Aromatic Compounds

cis-Cyclohexa-3,5-diene-1,2-diols 3, which are available by microbial oxidation of aromatic compounds, have been converted into 5-substituted conduritols D 5 by catalytic osmylation: application of the emthod to the preparation of homochiral 5-deuteriated