15411-17-3

Basic information

• Product Name: 1-(chlorodimethylsilyl)-2-(dichloromethylsilyl)ethane
• Synonyms: 1-(chlorodimethylsilyl)-2-(dichloromethylsilyl)ethane
• CAS NO: 15411-17-3
• Molecular Weight: 235.688
• Mol File: 15411-17-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(chlorodimethylsilyl)-2-(dichloromethylsilyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(chlorodimethylsilyl)-2-(dichloromethylsilyl)ethane(15411-17-3)
• EPA Substance Registry System: 1-(chlorodimethylsilyl)-2-(dichloromethylsilyl)ethane(15411-17-3)

Safety Data

• Hazardous Substances Data: 15411-17-3(Hazardous Substances Data)

Upstream product

• 1066-35-9 dimethylmonochlorosilane 
• 124-70-9 Dichloromethylvinylsilane 
• 75-54-7 Dichloromethylsilane 
• 1719-58-0 Chlorodimethylvinylsilane 

Downstream Products

• 75-77-4 chloro-trimethyl-silane 
• 6231-76-1 1,2-bis(trimethylsilyl)ethane 
• 754-05-2 ethenyltrimethylsilane 

Relevant articles and documents

Synthesis of unsymmetrical 1,2-bis(diorganochlorosilyl)ethanes

Unsymmetrical 1,2-bis(diorganylsilyl)ethanes were synthesized by two procedures. Hydrosilylation of chloro(vinyl)silanes were used to obtain compounds of the general formula ClMe2SiCH2CH 2SiRMeCl with different substituents (R = Et, Vin, Ph) on the silicon atom. Chlorodealkylation of 1,2-bis(trialkylsilyl)ethanes gave compounds of the general formula ClAlk2SiCH2CH2SiAlk 2Cl (Alk = Me, Et, Pr). It is established that the latter reaction provides high yields only with Me-and Et-substituted compounds, whereas Pr-substituted products are formed in poor yields. The mechamism of this reaction based on quantum-chemical calculations is offered.

SIDE REACTIONS IN THE HYDROSILYLATION OF VINYLSILANES IN PRESENCE OF SPEIER'S CATALYST

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