1542249-05-7

Basic information

• Product Name: C₁₂H₂₇N
• Synonyms: C₁₂H₂₇N
• CAS NO: 1542249-05-7
• Molecular Weight: 185.353
• Mol File: 1542249-05-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₂H₂₇N(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₂₇N(1542249-05-7)
• EPA Substance Registry System: C₁₂H₂₇N(1542249-05-7)

Safety Data

• Hazardous Substances Data: 1542249-05-7(Hazardous Substances Data)

Upstream product

• 124-11-8 non-1-ene 
• 107-31-3 Methyl formate 
• 124-40-3 dimethyl amine 

Relevant articles and documents

Methylformate as replacement of syngas in one-pot catalytic synthesis of amines from olefins

A new general approach for the one-pot hydroaminomethylation of olefins using methylformate as formylating agent instead of synthesis gas (syngas) has been proposed. Herein we report that a Ru-Rh catalytic system demonstrates high activity in a tandem conversion of a series of n-alkenes into amines using methylformate with yields 58-92% (6 h). The selectivity for the normal amine reached 96% with catalysis by the Ru carbonyl complex Ru3(CO) 12, with an overall yield of 55% with respect to amine in this instance. The addition of the Rh complex to Ru catalytic system, sharply increased the hydroaminomethylation rate of both the terminal and internal alkenes and increased the yield of amines to 82-93% (6-12 h). The Royal Society of Chemistry.