155049-45-9

Basic information

• Product Name: methyl-2,3,4-tri-O-acetyl-6-deoxy-α-D-luxo-hex-5-enopyranoside
• Synonyms: methyl-2,3,4-tri-O-acetyl-6-deoxy-α-D-luxo-hex-5-enopyranoside
• CAS NO: 155049-45-9
• Molecular Weight: 302.281
• Mol File: 155049-45-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl-2,3,4-tri-O-acetyl-6-deoxy-α-D-luxo-hex-5-enopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-2,3,4-tri-O-acetyl-6-deoxy-α-D-luxo-hex-5-enopyranoside(155049-45-9)
• EPA Substance Registry System: methyl-2,3,4-tri-O-acetyl-6-deoxy-α-D-luxo-hex-5-enopyranoside(155049-45-9)

Safety Data

• Hazardous Substances Data: 155049-45-9(Hazardous Substances Data)

Upstream product

• 50692-55-2 methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-mannopyranoside 
• 141-78-6 ethyl acetate 

Downstream Products

• 7432-72-6 methyl 2,3,4-tri-O-acetyl-α-D-mannopyranoside 
• 155049-46-0 methyl 2,3,4-tri-O-benzyl-5-methylene-α-D-lyxopyranoside 

Relevant articles and documents

A study of the epoxidation of 6-deoxyhex-5-enopyranosides. 1,5-Dicarbonyl derivatives and novel synthetic routes to D-xylo-hexos-5-ulose and D-lyxo-hexos-5-ulose

The work described deals with the isolation and characterization of epoxides from 6-deoxyhex-5-enopyranosides and preliminary exploration of their synthetic potential. Prolonged epoxidation reaction times led to their hydrolysis in situ and gave novel protected D-hexos-5-ulose derivatives (sugar 1,5-dicarbonyls). Some reactions of the hexos-5-uloses were studied, and in some cases septanoside (seven-membered-ring saccharide) derivatives were isolated. Novel routes to D-xylohexos-5-ulose and D-lyxo-hexos-5-ulose, of interest as intermediates in the synthesis and biosynthesis of inositols and aza sugars, are also described. The structures of the epoxides and novel hexos-5-uloses were established by NMR and X-ray crystallographic methods.