15517-46-1Relevant articles and documents
1,4-di(4-hydroxylbenzoyl)benzene monomer preparation method
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Paragraph 0019; 0020, (2017/10/10)
The invention relates to a high polymer material preparation method, in particular to a 1,4-di(4-hydroxylbenzoyl)benzene monomer preparation method. The method includes: selecting nitrobenzene as a solvent, aluminum trichloride as a catalyst and paraphtha
Visible Light Copper Photoredox-Catalyzed Aerobic Oxidative Coupling of Phenols and Terminal Alkynes: Regioselective Synthesis of Functionalized Ketones via C C Triple Bond Cleavage
Sagadevan, Arunachalam,Charpe, Vaibhav Pramod,Ragupathi, Ayyakkannu,Hwang, Kuo Chu
supporting information, p. 2896 - 2899 (2017/03/11)
Direct oxidative coupling of phenols and terminal alkynes was achieved at room temperature by a visible-light-mediated copper-catalyzed photoredox process. This method allows regioselective synthesis of hydroxyl-functionalized aryl and alkyl ketones from simple phenols and phenylacetylene via C C triple bond cleavage. 47 examples were presented. From a synthetic perspective, this protocol offers an efficient synthetic route for the preparation of pharmaceutical drugs, such as pitofenone and fenofibrate.