15540-09-7Relevant articles and documents
Cyclopentane construction by Rh-catalyzed intramolecular C-H insertion: Relative reactivity of a range of catalysts
Taber, Douglass F.,Joshi, Pramod V.
, p. 4276 - 4278 (2004)
The preparation and Rh-mediated cyclization of the α-diazoester 1 are outlined, and its utility in determining the elements that contribute to the reactivity of the intermediate Rh-carbenoid is presented. The rate of disappearance of diazo ester 1 catalyz
REDUCTION OF BENZYLIDENEACETONE DERIVATIVES WITH Pd/SiO2-AlPO4 AS CATALYST AND CYCLOHEXENE AS HYDROGEN DONOR
Alba, A.,Aramendia, A.,Borau, V.,Garcia-Raso, A.,Jimenez, C.,Marinas, J. M.
, p. 917 - 921 (2007/10/02)
The hydrogen transfer reduction of benzylidenacetone derivatives p-X-C6H4-CH=CH-CO-R (X=-OCH3, H; R=C6H5, alkyl, OR, OH) using cyclohexene as hydrogen donor has been studied.The selective reduction of the C=C bond is observed and the effects of the nature of X and R, solvent, catalyst, and reaction temperature on the initial reaction rate are analyzed.In all cases, and for any substrate or catalyst, the reaction is firts-order with respect to the hydrogen donor and acceptor.