1554455-85-4Relevant articles and documents
A general metal free approach to α-ketoamides via oxidative amidation-diketonization of terminal alkynes
Deshidi, Ramesh,Kumar, Manjeet,Devari, Shekaraiah,Shah, Bhahwal Ali
supporting information, p. 9533 - 9535 (2014/08/18)
A novel catalytic system TMSOTf/I2/DMSO for the oxidative coupling of terminal alkynes with virtually any primary/secondary amine leading to α-ketoamides has been developed. The reaction possibly proceeds via iminium ion formation, wherein DMSO acts as a solvent as well as an oxidizing agent. This journal is the Partner Organisations 2014.