15545-32-1Relevant articles and documents
Ag-Cu copromoted direct C2-H bond thiolation of azoles with Bunte salts as sulfur sources
Du, Xiao,Hu, Yuntao,Wang, Rui,Wei, Yingsu,Xu, Hongyan,Zhang, Ying,Zhao, Huaiqing
supporting information, p. 5899 - 5904 (2021/07/12)
A direct C2-H thiolation of azoles with Bunte salts was achieved under the combined action of copper and silver salts. This protocol could furnish various substituted 2-thioazoles in moderate to good yields. This method has a broad substrate scope and shows good functional group tolerance.
Addition of trimethylsulfoxoniumylide and methylenetriphenylphosphorane to N2-thioacylamidines
Toure, S. A.,Voglozin, A.,Degny, E.,Danion-Bougot, R.,Danion, D.,et al.
, p. 574 - 579 (2007/10/02)
Trimethylsulfoxonium ylide reacts with 4-dimethylamino-1-thia-3-azabutadienes (N2-thioacylamidines) affording thiazol-2-ines, through a regioselective reaction corresponding to a nucleophilic attack on the amidine group.Thiazoles are obtained b
