155486-94-5

Basic information

• Product Name: (2R,3S)-2-<(R)-p-tolylsulfinyl>-1-(trimethylsilyl)-3-octanol
• Synonyms: (2R,3S)-2-<(R)-p-tolylsulfinyl>-1-(trimethylsilyl)-3-octanol
• CAS NO: 155486-94-5
• Molecular Weight: 340.602
• Mol File: 155486-94-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S)-2-<(R)-p-tolylsulfinyl>-1-(trimethylsilyl)-3-octanol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S)-2-<(R)-p-tolylsulfinyl>-1-(trimethylsilyl)-3-octanol(155486-94-5)
• EPA Substance Registry System: (2R,3S)-2-<(R)-p-tolylsulfinyl>-1-(trimethylsilyl)-3-octanol(155486-94-5)

Safety Data

• Hazardous Substances Data: 155486-94-5(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 66-25-1 hexanal 
• 153123-09-2 (R_S)-p-Tolyl β-(trimethylsilyl)ethyl sulfoxide 

Downstream Products

• 3391-86-4 (S)-oct-1-en-3-ol 

Relevant articles and documents

Vinyl Anion Equivalent V. Asymmetric Synthesis of Allylic Alcohols Using Chiral 2-(Trialkylsilyl)ethyl Sulfoxides

Both enantiomers of optically pure secondary allylic alcohols can be conveniently prepared by the diastereoselective reaction of the α-sulfinyl carbanion of p-tolyl 2-(trialkylsilyl)ethyl sulfoxides or tert-butyl 2-(trimethylsilyl)ethyl sulfoxide with aldehydes followed by either fluoride-induced desilylsulfinylation or thermal elimination of the sulfinyl group.