155787-75-0

Basic information

• Product Name: (E)-4-(4-(3,4-diacetoxybenzylidene)-5-oxo-4,5-dihydrofuran-2-yl)-1,2-phenylene diacetate
• Synonyms: (E)-4-(4-(3,4-diacetoxybenzylidene)-5-oxo-4,5-dihydrofuran-2-yl)-1,2-phenylene diacetate
• CAS NO: 155787-75-0
• Molecular Weight: 480.428
• Mol File: 155787-75-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-4-(4-(3,4-diacetoxybenzylidene)-5-oxo-4,5-dihydrofuran-2-yl)-1,2-phenylene diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-(4-(3,4-diacetoxybenzylidene)-5-oxo-4,5-dihydrofuran-2-yl)-1,2-phenylene diacetate(155787-75-0)
• EPA Substance Registry System: (E)-4-(4-(3,4-diacetoxybenzylidene)-5-oxo-4,5-dihydrofuran-2-yl)-1,2-phenylene diacetate(155787-75-0)

Safety Data

• Hazardous Substances Data: 155787-75-0(Hazardous Substances Data)

Upstream product

• 67727-64-4 3,4-diacetoxybenzaldehyde 
• 155787-74-9 5-(3,4-diacetoxyphenyl)-2(3H)-furanone 
• 88623-81-8 3,4-diacetoxycinnamic acid 
• 66373-95-3 4-bromo-1,2-phenylene diacetate 
• 5333-34-6 3-(3,4-dimethoxybenzoyl)propionic acid 
• 57596-02-8 3-(3,4-dihydroxybenzoyl)propionic acid 

Downstream Products

• 145588-13-2 (E)-3-(3,4-dihydroxybenzylidene)-5-(3,4-dihydroxyphenyl)-2(3H)-furanone 

Relevant articles and documents

Stereoselective synthesis of: E -3-(arylmethylidene)-5-(alkyl/aryl)-2(3 H)-furanones by sequential hydroacyloxylation-Mizoroki-Heck reactions of iodoalkynes

A modular, stereoselective synthesis of E-3-(arylidene)-5-(alkyl/aryl)-2(3H)-furanones was developed. The methodology features regioselective addition of β-aryl acrylic acids to iodoacetylenes to furnish the Z-acyloxy iodoalkenes. A stereoselective 5-exo-trig Mizoroki-Heck reaction of the acyloxy iodoalkenes generates the target E-2(3H)-furanones. The approach was applied in a formal synthesis of the naturally occurring kinase inhibitor BE-23372M.