155804-86-7

Basic information

• Product Name: [Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]⁽¹⁺⁾*BF₄^(1-)=[Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]BF₄
• Synonyms: [Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]⁽¹⁺⁾*BF₄^(1-)=[Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]BF₄
• CAS NO: 155804-86-7
• Molecular Weight: 665.774
• Mol File: 155804-86-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]⁽¹⁺⁾*BF₄^(1-)=[Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]⁽¹⁺⁾*BF₄^(1-)=[Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]BF₄(155804-86-7)
• EPA Substance Registry System: [Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]⁽¹⁺⁾*BF₄^(1-)=[Pd(P(C₆H₅)3)(C₅NH₄C(CH₃)NNHC₆H₄)]BF₄(155804-86-7)

Safety Data

• Hazardous Substances Data: 155804-86-7(Hazardous Substances Data)

Upstream product

• 7734-05-6 2-acetylpyridine phenylhydrazone 
• 155804-82-3 [Pd(C₆H₅N(H)N=CMe(C₅H₄N))(Cl₂)] 
• 28625-02-7 thallium(I) tetrafluoroborate 
• 155804-84-5 [Pd(C₆H₄N(H)N=CMe(C₅H₄N))(Cl)] 

Relevant articles and documents

Cyclopalladated complexes of 2-acetylpyridine phenylhydrazone: A terdentate C,N,N′ donor ligand

Cyclopalladated complexes of 2-acetylpyridine phenylhydrazone [Pd(C6H4N(H)N=C(CH3)-C5H 4N)Cl] (2) and [Pd(C6H4N(H)N=C(CH3)C5H 4N)L]BF4 (L = PPh3 (3a), P(OMe)3 (3b), P(OPh)3 (3c), CH3C5H4N (3d), C4H8S (3e)) containing readily deprotonable N-H bonds have been prepared. Blue zwitterionic species, obtained after deprotonation of the cationic complexes, are characterized by their reactivity as nucleophiles toward H+ or CH3I; e.g. deprotonated (3a) reacts with CH3I to give [Pd(C6H4N(CH3)N=C(CH3)C 5H4N)I] (5). Some aspects of the orthometalation reaction mechanism of phenylhydrazones are discussed. The crystal and molecular structure of the face to face complex {[Pd(C6H4N(H)N=C(CH3)C5H 4N)]2(μ-Ph2PCH2PPh 2)}[BF4]2·OEt2·NCMe (4) [monoclinic, space group P21/n, a = 15.911(4) A?, b = 18.902-(6) A?, c = 18.563(4) A?, β = 95.43(2)°, Z = 4, R = 0.032, and Rw = 0.034 for 7038 observed reflections] shows a nonbonding Pd-Pd distance of 3.114(1) A?.