155855-52-0

Basic information

• Product Name: (1R,2S,6S,7S)-4,4-dimethyl-9-phenyl-3,5,8-trioxa-9-aza-tricyclo[5.2.1.0^2,6]decane
• Synonyms: (1R,2S,6S,7S)-4,4-dimethyl-9-phenyl-3,5,8-trioxa-9-aza-tricyclo[5.2.1.0^2,6]decane
• CAS NO: 155855-52-0
• Molecular Weight: 247.294
• Mol File: 155855-52-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,2S,6S,7S)-4,4-dimethyl-9-phenyl-3,5,8-trioxa-9-aza-tricyclo[5.2.1.0^2,6]decane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,6S,7S)-4,4-dimethyl-9-phenyl-3,5,8-trioxa-9-aza-tricyclo[5.2.1.0^2,6]decane(155855-52-0)
• EPA Substance Registry System: (1R,2S,6S,7S)-4,4-dimethyl-9-phenyl-3,5,8-trioxa-9-aza-tricyclo[5.2.1.0^2,6]decane(155855-52-0)

Safety Data

• Hazardous Substances Data: 155855-52-0(Hazardous Substances Data)

Upstream product

• 38838-06-1 methyl 5-deoxy-5-iodo-2,3-isopropylidene-β-D-ribofuranoside 
• 155934-55-7 (4R,5R)-2,2-dimethyl-5-vinyl-[1,3]dioxolane-4-carbaldehyde 
• 1026454-37-4 C₁₄H₁₇NO₃ 
• 1026454-37-4 C₁₄H₁₇NO₃ 

Downstream Products

• 155855-55-3 (3aR,4S,6R,6aS)-6-anililino-2,2-dimethyl-tetrahydro-3aH-cyclopenta[d][1,3]dioxol-4-ol 

Relevant articles and documents

An improved approach to chiral cyclopentenone building blocks. Total synthesis of pentenomycin I and neplanocin A

An improved approach to enantiomerically pure hydroxylated cyclopentenones is reported here, which involves intramolecular nitrone cycloaddition of sugar-derived chiral pent-4-enals and hex-5-en-ones-2 followed by N-O bond cleavage, quaternization of the amine thus produced, and finally oxidative elimination of the amino group. Synthesis of pentenomycin I and neplanocin A is described following this methodology.