155912-26-8Relevant articles and documents
Synthesis and characterization and crystal structure of new oxime-type mononuclear nickel(II) complex with 1-[4-((E)-4-methoxyl-2-hydroxybenzylidene)]oxime
Zhao,Wang,Cheng,Guo,Yan
, p. 8107 - 8109 (2014)
A new Ni(II) complex, [Ni(L)2], has been synthesized via the complexation of nickel(II) acetate monohydrate with a new oxime-type ligand (HL =1-[4-((E)-4-methoxyl-2-hydroxybenzylidene)]oxime). X-ray crystal structure determination of the Ni(II) complex shows that the Ni(II) complex is mononuclear, the Ni(II) atom is four-coordinated by the phenolate O atoms and imine N atoms from two deprotonated oxime-type ligands L-, in a square-planar geometry.
Salicylaldoxime ester compounds as well as preparation method and application thereof
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Paragraph 0038; 0039, (2018/05/16)
The invention discloses salicylaldoxime ester compounds with a structure shown in formula I. A substituent group R of the salicylaldoxime ester compounds is selected from C1-C8 alkyl, or selected fromcyanogroup, halogen, phenyl, C1-C4 alkoxy, C1-C4 alkyl sulphanyl substituted C1-C8 alkyl, or selected from phenyl, or selected from phenyl with 1-3 substituent groups, wherein the 1-3 substituent groups on phenyl are selected from halogen, hydroxyl, carboxyl, nitryl, cyano group, phenyl, phenoxyl, benzoyl, C1-C8 alkyl, C3-C8 naphthenic base, C1-C4 alkoxy, C1-C4 halogenated alkyl, C1-C4 halogenated alkoxy, C1-C4 halogenated alkyl sulphanyl and C1-C4 halogenated alkyl sulfonyl. According to a synthesis route of the salicylaldoxime ester compounds, 4-methoxyl salicylaldehyde and hydroxylamine hydrochloride are taken as raw materials. The method is used for the first time for synthesis of the compounds and has the advantages that the yield is high, separation is easy and the like. The compounds have better bacteriostatic activity for multiple agricultural pathogenic fungi.
Mild and efficient dehydration of oximes to nitriles mediated by the Burgess reagent
Miller,Kaufman
, p. 1169 - 1171 (2007/10/03)
Both aliphatic and aromatic aldoximes undergo dehydration to the corresponding nitriles in excellent yields by simply heating the oximes in THF with 1.5 equivalents of the Burgess reagent (methyl N-(triethylammonium-sulfonyl)carbamate,). The reaction also works well using the PEG-supported Burgess reagent and thus has considerable potential for the parallel synthesis of cyano-containing compound libraries.
