15602-41-2

Basic information

• Product Name: sodium hexacarbonylvanadate
• Synonyms: sodium hexacarbonylvanadate
• CAS NO: 15602-41-2
• Molecular Weight: 241.994
• Mol File: 15602-41-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: sodium hexacarbonylvanadate(CAS DataBase Reference)
• NIST Chemistry Reference: sodium hexacarbonylvanadate(15602-41-2)
• EPA Substance Registry System: sodium hexacarbonylvanadate(15602-41-2)

Safety Data

• Hazardous Substances Data: 15602-41-2(Hazardous Substances Data)

Upstream product

• 16940-66-2 sodium tetrahydroborate 
• 12085-80-2 (CH₃)3C₆H₃V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 
• 84517-94-2 (CH₃)3C₆H₃V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 
• 12112-48-0 (CH₃)6C₆V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 
• 12214-62-9 C₆H₆V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 
• 12087-53-5 (CH₃)4C₆H₂V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 
• 12085-81-3 (CH₃)3C₆H₃V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 
• 84517-92-0 (CH₃)2C₆H₄V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 
• 12088-95-8 C₆H₄(CH₃)2V(CO)4⁽¹⁺⁾*V(CO)6^(1-) 

Downstream Products

• 112713-44-7 methylacridinium hexacarbonylvanadate 
• 36643-83-1 tetracarbonyl{1,2-bis(diphenylphosphino)ethane}iodovanadium 
• 7681-82-5 sodium iodide 
• 14024-00-1 vanadium hexacarbonyl 
• 20644-87-5 (hexacarbonyl)vanadinate^(1-) 
• 34089-18-4 {(C₂H₅)4N}⁽¹⁺⁾*{V(CO)5Sb(C₆H₅)3}^(1-)={(C₂H₅)4N}{V(CO)5Sb(C₆H₅)3} 
• 27323-98-4 (C₆H₅)3SnV(CO)6 
• 89669-25-0 (C₆H₅)3PbV(CO)6 
• 18347-09-6 tetracarbonylvanadium⁽⁰⁾(1,2-bis(diphenylphosphino)ethane) 

Relevant articles and documents

The reaction of hexacarbonylvanadium with aromatic compounds. III. Reduction of the [V(CO)4arene]+ cations to tetracarbonyl-π-cyclohexadienylvanadium derivatives

The hexacarbonylvanadate of the [V(CO)4C6H6]+ cation reacts with sodium tetrahydridoborate to give the red crystalline volatile V(CO)4C6H7 in about 60% yield. On the basis of infrared and nmr data this is shown to be tetracarbonyl-π-cyclohexadienylvanadium. Methyl-substituted cyclohexadienyl compounds V(CO)4C6H7-n(CH3)n are also described, being obtained by reduction of the methyl-substituted arene vanadium compounds [V(CO)4C6H6-n(CH3)n] +. Similar reactions with NaBD4 yielded the corresponding deuterated compounds. The nmr spectra suggest that the addition of hydrogen occurs preferentially at unsubstituted positions of the aromatic ring in [V(CO)4C6H6-n(CH3)n] +. The type of bonding between the metal and the cyclohexadienyl system and the conformation of the cyclohexadienyl ligand are briefly discussed.