15620-71-0Relevant articles and documents
Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light
Xia, Lixin,Hu, Xinhu,Sun, Mengtao,Li, Jushi,Yang, Donghui,Wang, Xiaofang,Xu, Hongxing
, p. 1024 - 1028 (2012/10/29)
For the first time, we report experimentally and theoretically that nitroaromatic compounds, 2,4-dinitrobenzenethiol and 4-chloro-2- nitrobenzenethiol, on silver sols can be selectively reduced to 2-amino-4-nitrobenzenethiol and 2-amino-4-chlorobenzenethiol simply by irradiating with a visible light in ambient conditions, and the selective photoreduction is a very facile process. The results of quantum chemical calculations are in good agreement with our experimental data. Copyright