15630-29-2

Basic information

• Product Name: trans-bis[1,3-(4-bromophenyl)triazenide] mercury(II)
• CAS NO: 15630-29-2
• Molecular Weight: 908.637
• Mol File: 15630-29-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-bis[1,3-(4-bromophenyl)triazenide] mercury(II)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-bis[1,3-(4-bromophenyl)triazenide] mercury(II)(15630-29-2)
• EPA Substance Registry System: trans-bis[1,3-(4-bromophenyl)triazenide] mercury(II)(15630-29-2)

Safety Data

• Hazardous Substances Data: 15630-29-2(Hazardous Substances Data)

Upstream product

• 1600-27-7 mercury(II) diacetate 
• 3470-38-0 1,3-bis-(4-bromo-phenyl)-triazene 

Relevant articles and documents

Unidimensional self-assembling of {HgII[NNN(PhBr) 2]2} through metal-η4-arene π-interactions: Synthesis and x-ray characterization of a bis diaryl symmetric-substituted triazenide complex polymer of mercury(II)

A solution of deprotonated 1,3-bis(4-bromophenyl)triazene reacts with Hg(CH3COO)2 in methanol / tetrahydrofurane to give yellow crystalline needles of {HgII[NNN(PhBr)2]2} n, a triazenide complex polymer of HgII with metal-η2,η2-arene π-interactions, performed by coordinated single triazenide chains. The crystal structure of the new polymeric complex of HgII belongs to the monoclinic space group P2 1/n. The lattice of [HgII(BrPhNNNPhBr)2] n can be viewed as a one-dimensional assembling of planar tectons [HgII(BrPhNNNPhBr)2] linked through metalocene alike HgII-η2,η2-arene π-interactions along the crystallographic b axis.