1563186-91-3

Basic information

• Product Name: C₂₈H₄₂FNOSn
• Synonyms: C₂₈H₄₂FNOSn
• CAS NO: 1563186-91-3
• Molecular Weight: 546.356
• Mol File: 1563186-91-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₈H₄₂FNOSn(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₈H₄₂FNOSn(1563186-91-3)
• EPA Substance Registry System: C₂₈H₄₂FNOSn(1563186-91-3)

Safety Data

• Hazardous Substances Data: 1563186-91-3(Hazardous Substances Data)

Upstream product

• 813-19-4 bis(tri-n-butyltin) 
• 98-88-4 benzoyl chloride 
• 82605-86-5 Ethyl-[1-(4-fluoro-phenyl)-meth-(E)-ylidene]-amine 

Relevant articles and documents

Palladium-catalyzed stille-type coupling of N -acyl iminium ions with distannanes: A Multicomponent synthesis of α-amidostannanes

The palladium-catalyzed three-component coupling of imines, acid chlorides, and hexabutyldistannane is described. This results in the synthesis of various α-amidostannanes in good yields, without the use of strong nucleophilic organometallic reagents. The reaction is believed to proceed via a Stille-type cross coupling of an in situ-generated N-acyl iminium salt with Bu 3SnSnBu3 and reaches completion within 1 h at ambient temperature using simple, unligated Pd2dba3 as a catalyst. Combining the formation of α-amidostannanes with lithiation and carboxylation allows the overall synthesis of amino acid derivatives in two steps from imines, acid chlorides, and CO2.