156492-31-8Relevant articles and documents
Tris(1,10-phenanthroline)iron(II) Complexes. Influence of 4,7-Donor Substitution on the Redox Potential
Levis, Michael,Luening, Ulrich,Mueller, Michael,Schmittel, Michael,Woehrle, Clemens
, p. 675 - 682 (2007/10/02)
Several new 4,7-donor substituted 1,1-phenanthrolines were synthesized and the corresponding tris(1,10-phenanthroline)iron(II) complexes were studied by cyclic voltammetry.All iron(II) complexes showed fully reversible waves at scan rates between 50 and 500 mV/s.For some redox systems the kinetics in their reaction with chlorine was studied.Complexes 7k and 7l significantly extent the potential range of tris(1,10-phenanthroline)iron(II) complexes. - Keywords: Redox Potential, Cyclic Voltammetry, Electron Transfer, Kinetics with Chlorine