156570-79-5Relevant articles and documents
Studies toward the total synthesis of angelmicin B (hibarimicin B): Synthesis of a model CD-D′ arylnaphthoquinone
Narayan, Sridhar,Roush, William R.
, p. 3789 - 3792 (2007/10/03)
(Chemical Equation Presented) A synthesis of arylnaphthoquinone 22 corresponding to the CD-D′ unit of angelmicin B via the Suzuki coupling of the D′ arylboronic acid 15 with the CD bromonaphthoquinone 21 is described. The mild conditions for the Suzuki cross-coupling leading to 22 may prove to be useful for the eventual late-stage coupling of the two highly functionalized halves of angelmicin B.