156670-82-5

Basic information

• Product Name: TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))
• Synonyms: TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))
• CAS NO: 156670-82-5
• Molecular Weight: 630.035
• Mol File: 156670-82-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))(CAS DataBase Reference)
• NIST Chemistry Reference: TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))(156670-82-5)
• EPA Substance Registry System: TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))(156670-82-5)

Safety Data

• Hazardous Substances Data: 156670-82-5(Hazardous Substances Data)

Upstream product

• 146733-16-6 tetrachloro(1,2-dimethoxyethane-O,O')tungsten(IV) 
• 31011-57-1 tetrachlorobis(tetrahydrofuran)titanium(IV) 
• 160544-65-0 Li⁽¹⁺⁾*N(C(C⁽²⁾H₃)2CH₃)(C₆H₃(CH₃)2)^(1-)*(C₂H₅)2O=Li(N(C(C⁽²⁾H₃)2CH₃)(C₆H₃(CH₃)2))*(C₂H₅)2O 

Relevant articles and documents

Synthesis of mer-trichlorotris(tetrahydrofuran)tungsten (III) by intermetal chlorine atom transfer

The three-coordinate titanium(III) complex Ti(N[R]Ar)3 (R = C(CD3)2CH3, Ar = 3,5-C6H3Me2) abstracts chlorine from WCl4(DME) (DME = 1,2-dimethoxyethane) in tetrahydrofuran (THF) to give yellow crystalline WCl3(THF)3 in 65% isolated yield. Orange TiCl(N[R]Ar)3, which can be recycled to Ti(N[R]Ar)3 in 73% yield by reduction with sodium amalgam, was recovered in 71% yield. WCl3(THF)3 was characterized by elemental analysis, SQUID magnetic susceptibility measurements, 1H NMR spectroscopy and single crystal X-ray crystallography. WCl3(THF)3 was found to be an octahedral complex possessing a meridional arrangement of ligands, as has been seen for other MCl3(THF)3 complexes (M = Sc, Ti, V, Cr, Mo).