156976-27-1

Basic information

• Product Name: {Ag(I)(C₄H₈NCS₂)(bis(diphanylphosphanyl)-o-carborane)}
• CAS NO: 156976-27-1
• Molecular Weight: 766.707
• Mol File: 156976-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {Ag(I)(C₄H₈NCS₂)(bis(diphanylphosphanyl)-o-carborane)}(CAS DataBase Reference)
• NIST Chemistry Reference: {Ag(I)(C₄H₈NCS₂)(bis(diphanylphosphanyl)-o-carborane)}(156976-27-1)
• EPA Substance Registry System: {Ag(I)(C₄H₈NCS₂)(bis(diphanylphosphanyl)-o-carborane)}(156976-27-1)

Safety Data

• Hazardous Substances Data: 156976-27-1(Hazardous Substances Data)

Upstream product

• 156976-04-4 {Ag(I)(ClO₄)(bis(diphanylphosphanyl)-o-carborane)} 
• 872-71-9 sodium pyrrolidine-N-carbodithioate 

Relevant articles and documents

Synthesis of Silver(I) Complexes with the Bis(diphenylphosphanyl)-o-carborane Ligand. Crystal Structure of >ClO4 and >ClO4*CH2Cl2

Silver perchlorate or nitrate react readily with bis(diphenylphosphanyl)-o-carborane to give the complexes > .The perchlorate ligand is weakly bound to the silver atom and thus can be displaced by other ligands affording the three-coordinated complexes >ClO4 .Compounds 3 and 4 can also be obtained by reaction of with the diphosphane.Treatment of complex 1 with bidentate ligands leads to the cationic four-coordinated >ClO4 or to the neutral > .The crystal structures of 11 and 12 have been established by X-ray crystallography.In both complexes the silver(I) atoms exhibit tetrahedral coordination by two phosphorus and two nitrogen or two sulfur atoms, respectively. - Key Words: Silver(I) complexes / Bis(diphenylphosphanyl)-o-carborane / o-Carborane