156994-84-2Relevant articles and documents
Tin/mercury exchange in 1,2-distannyl-1-alkenes and 1-silyl-2-stannyl-1-alkenes
Mitchell, T. N.,Kowall, B.
, p. 39 - 42 (2007/10/02)
1,2-Bis(chloromercuri)alkenes, 1-trimethylsilyl-2-chloromercuri-alkenes and 1-trimethylsilyl-2-organomercurialkenes can be readily made by transmetallation of the corresponding trimethyltin compounds with HgCl2 and RHgCl; their structures have been confirmed by multinuclear NMR data.The new compounds are expected to have a large synthetic potential involving lithium/mercury exchange, and subsequent reaction with electrophilic reagents.Key words: Mercury; Nuclear magnetic resonance; Tin; Silicon