1573176-40-5

Basic information

• Product Name: 5,15-bis{9,10-di(naphth-2-yl)anthr-2-ylethynyl}-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)
• Synonyms: 5,15-bis{9,10-di(naphth-2-yl)anthr-2-ylethynyl}-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)
• CAS NO: 1573176-40-5
• Molecular Weight: 1648.77
• Mol File: 1573176-40-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5,15-bis{9,10-di(naphth-2-yl)anthr-2-ylethynyl}-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)(CAS DataBase Reference)
• NIST Chemistry Reference: 5,15-bis{9,10-di(naphth-2-yl)anthr-2-ylethynyl}-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)(1573176-40-5)
• EPA Substance Registry System: 5,15-bis{9,10-di(naphth-2-yl)anthr-2-ylethynyl}-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II)(1573176-40-5)

Safety Data

• Hazardous Substances Data: 1573176-40-5(Hazardous Substances Data)

Upstream product

• 474688-76-1 2-bromo-9,10-di(2-naphthyl)anthracene 
• 1573176-38-1 5,15-diethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin Ni(II) 

Downstream Products

• 1573176-43-8 2-(9,10-di(naphth-2-yl)anthr-2-yl)acetic acid 
• 175444-05-0 5,15-(di-3,5-di-tert-butylphenyl)porphyrinato nickel(II) 

Relevant articles and documents

Silylethynyl substituents as porphyrin protecting groups for solubilization and selectivity control

Silylethynyl substituents are proposed as protecting groups for porphyrin derivatives to enhance their solubility and enable regioselective functionalization. After usage as protecting groups, silylethynyl groups at the meso-positions can be efficiently removed upon heating with aqueous H 2SO4 in the presence of a surfactant. This approach was applied to the preparation of unsymmetrically β-substituted porphyrins and porphin-porphyrin oligomers, which were inaccessible by conventional methods.