157367-96-9

Basic information

• Product Name: 4-methyl-N-(4-methylpent-4-en-1-yl)benzenesulfonamide
• Synonyms: 4-methyl-N-(4-methylpent-4-en-1-yl)benzenesulfonamide
• CAS NO: 157367-96-9
• Molecular Weight: 253.365
• Mol File: 157367-96-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 4-methyl-N-(4-methylpent-4-en-1-yl)benzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-(4-methylpent-4-en-1-yl)benzenesulfonamide(157367-96-9)
• EPA Substance Registry System: 4-methyl-N-(4-methylpent-4-en-1-yl)benzenesulfonamide(157367-96-9)

Safety Data

• Hazardous Substances Data: 157367-96-9(Hazardous Substances Data)

Upstream product

• 70-55-3 toluene-4-sulfonamide 
• 349098-69-7 N-(4-methylpentyl)-4-methylbenzenesulfonamide 
• 25163-50-2 4-methyl-4-pentenyl-1-tosylate 
• 1071-73-4 5-Hydroxy-2-pentanone 
• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 
• 22508-64-1 4-methyl-4-penten-1-ol 
• 691900-28-4 N-(tert-butoxycarbonyl)-N-(4-methylpent-4-enyl)-4-methylbenzenesulfonamide 
• 73541-16-9 5-iodo-2-methylpent-1-en 

Downstream Products

• 691900-33-1 N-formyl-N-(4-methylpent-4-enyl)-4-methylbenzenesulfonamide 
• 1403817-97-9 (+/-)-(2-methyl-1-tosylpyrrolidin-2-yl)methanol 
• 1322093-54-8 2-(bromomethyl)-2-methyl-1-tosylpyrrolidine 
• 691900-36-4 N-(2,2-dichlorovinyl)-N-(4-methylpent-4-enyl)-4-methylbenzenesulfonamide 
• 691900-13-7 N-ethynyl-4-methyl-N-(4-methyl-pent-4-enyl)-benzenesulfonamide 

Relevant articles and documents

Aza-heterocycles via copper-catalyzed, remote C–H desaturation of amines

A majority of medicines contain a nitrogen atom within a five- or six-membered ring. To rapidly access both such aza-heterocycles, we sought to develop a remote C–H desaturation of amines. Inspired by the Hofmann-L?ffler-Freytag (HLF) synthesis of five-me

Rhodium-Catalyzed Alkene Difunctionalization with Nitrenes

The RhII-catalyzed oxyamination and diamination of alkenes generate 1,2-amino alcohols and 1,2-diamines, respectively, in good to excellent yields and with complete regiocontrol. In the case of diamination, the intramolecular reaction provides

Radical cascade cyclizations and platinum(II)-catalyzed cycloisomerizations of ynamides

Ynamides are tested as new partners in radical and organometallic transformations. A radical cascade involving a 5-exo-dig cyclization followed by a 6-endo-trig radical trapping transforms ynamides into hetero-polycyclic compounds such as isoindoles, isoindolinones and pyrido-isoindolones. Various ene-tosylynamides react with platinum(II) chloride and lead to bicyclic nitrogenated heterocycles. This unprecedented and easily operated process can be coupled with a hydrolysis of the intermediate cyclic tosylenamides in a one-pot transformation, which provides cyclobutanones.