157394-45-1Relevant articles and documents
Asymmetric Induction by a Nitrogen14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis
Matsumoto, Arimasa,Ozaki, Hanae,Harada, Shunya,Tada, Kyohei,Ayugase, Tomohiro,Ozawa, Hitomi,Kawasaki, Tsuneomi,Soai, Kenso
supporting information, p. 15246 - 15249 (2016/12/03)
Chirality arising from isotope substitution, especially with atoms heavier than the hydrogen isotopes, is usually not considered a source of chirality in a chemical reaction. An N2,N2,N3,N3-tetramethyl-2,3-butan
A Simple Method for Chelation Controlled Additions to α-Amino Aldehydes
Reetz, Manfred T.,Roelfing, Karin,Griebenow, Nils
, p. 1969 - 1972 (2007/10/02)
BOC- and Cbz-protected α-amino aldehydes derived from amino acids undergo stereoselective addition reactions with alkyl cuprates and manganese reagents, the chelation-controlled adducts being the major diastereomers (generally ds > 90percent).Undesired ra