157430-13-2

Basic information

• Product Name: p-methoxyphenyl 2,3,6-trideoxy-α-L-erythro-hex-2-enepyranoside
• Synonyms: p-methoxyphenyl 2,3,6-trideoxy-α-L-erythro-hex-2-enepyranoside
• CAS NO: 157430-13-2
• Molecular Weight: 236.268
• Mol File: 157430-13-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: p-methoxyphenyl 2,3,6-trideoxy-α-L-erythro-hex-2-enepyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: p-methoxyphenyl 2,3,6-trideoxy-α-L-erythro-hex-2-enepyranoside(157430-13-2)
• EPA Substance Registry System: p-methoxyphenyl 2,3,6-trideoxy-α-L-erythro-hex-2-enepyranoside(157430-13-2)

Safety Data

• Hazardous Substances Data: 157430-13-2(Hazardous Substances Data)

Upstream product

• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 
• 150-76-5 4-methoxy-phenol 
• 53657-42-4 L-rhamnal 
• 160956-79-6 4'-methoxyphenyl 4-O-acetyl-2,3,6-trideoxy-1-O-α-L-erythro-hex-2-enopyranoside 

Downstream Products

• 157430-14-3 (2S,3S,6S)-6-(4-Methoxy-phenoxy)-2-methyl-3,6-dihydro-2H-pyran-3-ol 
• 54826-92-5 (5R,6S)-5,6-dihydro-5-hydroxy-6-methylpyran-2-one 

Relevant articles and documents

Phenolic ferrier reaction and its application to the natural product synthesis

Ferrier reaction between acetylglycals and phenols proceeded smoothly to give α-O-Δ2 glycosides predominantly. The products were converted to bio-active natural products.

Mitsunobu reactions of glycals with phenoxide nucleophiles are S(N)2'-selective

The C3-hydroxyl group of L-rhamnal (4) and D-glucal 7 underwent S(N)2'-selective Mitsunobu displacements with substituted phenoxide nucleophiles. These reactions provide access to the corresponding α-arylglycoside.