15750-73-9

Basic information

• Product Name: [Al(3-phenylpentane-2,4-dionate)3]
• CAS NO: 15750-73-9
• Molecular Weight: 552.603
• Mol File: 15750-73-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Al(3-phenylpentane-2,4-dionate)3](CAS DataBase Reference)
• NIST Chemistry Reference: [Al(3-phenylpentane-2,4-dionate)3](15750-73-9)
• EPA Substance Registry System: [Al(3-phenylpentane-2,4-dionate)3](15750-73-9)

Safety Data

• Hazardous Substances Data: 15750-73-9(Hazardous Substances Data)

Upstream product

• 5910-25-8 3-phenylpentane-2,4-dione 
• 71-43-2 benzene 

Downstream Products

• 50324-02-2 4,6-dimethyl-5-phenyl-1H-pyrimidin-2-one 
• 17697-92-6 4,5,6-trimethyl-2,5-dihydro-2-thioxopyrimidine 
• 7189-15-3 3,5-dimethyl-1,4-diphenyl-1H-pyrazole 

Relevant articles and documents

Extended coordination frameworks incorporating heterobimetallic squares

The molecular structure of aluminium and iron(III) complexes with 3-phenyl and 3-(4-pyridyl) (HL) substituted acetylacetonate ligands is appreciably distorted. For AlL3 and FeL3 this shows that the orientation of the side pyridyl-N donor atoms lone pairs is about 90 and 135° which favours the assembly of heterobimetallic square patterns in Al(Fe)L3 complexes with metal ions. This was employed for the modular construction of semi-regular heterobimetallic networks, in which the pyridyldiketonate ligands bridge pairs of Fe(Al)/Cd(Co) metal ions and support the structure of 1D and 2D coordination polymers. The unprecedented 2D structure of [Cd{AlL3}(CH3OH){NO3} 2]·2CHCl3 and Cd{AlL3}-(CH 3OH)Br2]·2CHCl3·2CH 3OH is based upon plane tiling by a set of heterobimetallic squares and octagons, while [Cd{FeL3}2(NO3) 2]·2H2O and [Co{AlL3}2Cl 2]·4CHCl3·2CH3OH are 1D polymers and exist as chains of heterobimetallic squares sharing opposite vertices.