1575707-08-2

Basic information

• Product Name: tert-butyl ((1R,2S)-2-((3,5-dimethoxyphenyl)ethynyl)-1,2-dihydronaphthalen-1-yl)carbamate
• Synonyms: tert-butyl ((1R,2S)-2-((3,5-dimethoxyphenyl)ethynyl)-1,2-dihydronaphthalen-1-yl)carbamate
• CAS NO: 1575707-08-2
• Molecular Weight: 405.494
• Mol File: 1575707-08-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl ((1R,2S)-2-((3,5-dimethoxyphenyl)ethynyl)-1,2-dihydronaphthalen-1-yl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl ((1R,2S)-2-((3,5-dimethoxyphenyl)ethynyl)-1,2-dihydronaphthalen-1-yl)carbamate(1575707-08-2)
• EPA Substance Registry System: tert-butyl ((1R,2S)-2-((3,5-dimethoxyphenyl)ethynyl)-1,2-dihydronaphthalen-1-yl)carbamate(1575707-08-2)

Safety Data

• Hazardous Substances Data: 1575707-08-2(Hazardous Substances Data)

Upstream product

• 5176-28-3 N-(tert-butoxycarbonyl)-1,4-dihydro-1,4-iminonaphthalene 
• 171290-52-1 1-Ethynyl-3,5-dimethoxy-benzene 

Relevant articles and documents

Palladium/copper complexes co-catalyzed highly enantioselective ring opening reaction of azabenzonorbornadienes with terminal alkynes

A chiral palladium/copper (Pd/Cu) cocatalytic system which could enable asymmetric ring opening reaction of azabenzonorbornadienes with terminal alkynes is reported. This system comprises palladium(II) acetate [Pd(OAc) 2]/(R)-xyl-Binap and copper(I) triflate (CuOTf). A good substrate scope was found, with excellent enantioselective outcomes (up to >99.9% ee). A reaction mechanism involving two metal complexes is also proposed.