15764-66-6

Basic information

• Product Name: Oxiranenonanol
• Synonyms: 9-(oxiran-2-yl)-nonan-1-ol;10,11-Epoxy-n-undecan-1-ol;10,11-epoxyundecyl-1-ol;10,11-epoxyundecan-1-ol;9-oxiranyl-nonan-1-ol;Oxiranenonanol;9-(2-Oxiranyl)-1-nonanol;undecenol oxide
• CAS NO: 15764-66-6
• Molecular Formula: C11H22O2
• Molecular Weight: 186.294
• Mol File: 15764-66-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Oxiranenonanol(CAS DataBase Reference)
• NIST Chemistry Reference: Oxiranenonanol(15764-66-6)
• EPA Substance Registry System: Oxiranenonanol(15764-66-6)

Safety Data

• Hazardous Substances Data: 15764-66-6(Hazardous Substances Data)

Upstream product

• 112-43-6 10-Undecen-1-ol 
• 105-54-4 butanoic acid ethyl ester 
• 22663-09-8 methyl 9-(oxiran-2-yl)nonanoate 

Downstream Products

• 60254-74-2 11-chloro-10-oxoundecanoic acid 
• 21220-97-3 Thioschwefelsaeure-S-<2-(2,11-dihydroxy-undecylamino)-ethyl>-ester 

Relevant articles and documents

An Inexpensive Air-Stable Titanium-Based System for the Conversion of Esters to Primary Alcohols

Polymethylhydroxiloxane, when combined with titanium(IV) isopropoxide, provides a convenient system for the conversion of esters to the corresponding primary alcohols in the presence of a wide range of functional groups.Reactions are carried out as mixtures of the neat reaction components; workup with aqueous alkaline THF affords primary alcohols in good to excellent yields.The system tolerates primary alkyl bromides and iodides, olefins, epoxides, and alkynes.Steric differentiation of methyl and tert-butyl esters is also possible.The results observed in the parent and related reactions argue against pathways involving Lewis-acid catalysis and anionic hydridosilicate-mediated reductions, and instead support a neutral titanium hydride complex or strongly associated titanium/silane complex as the active reducing agent.