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15780-28-6

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15780-28-6 Usage

Description

Sodium deuteride is a chemical compound consisting of sodium and deuterium, an isotope of hydrogen. It appears as a gray powder and is sensitive to moisture. The compound is typically available as a 20% solution in oil, with a high isotopic purity of 98%.

Uses

Used in Nuclear Industry:
Sodium deuteride is used as a neutron source for various applications in the nuclear industry. The reason for its use is due to its ability to generate neutrons when bombarded with high-energy particles, making it a valuable tool for research and development in nuclear technology.
Used in Chemical Industry:
In the chemical industry, sodium deuteride is used as a reducing agent for certain chemical reactions. Its application is based on its ability to donate deuterium, which can be used to label compounds and study their behavior in various chemical processes.
Used in Research and Development:
Sodium deuteride is also utilized in research and development for its unique properties. It is used as a tracer in isotope labeling studies, allowing scientists to track the movement and reactions of specific molecules within complex systems. This application is valuable for understanding the mechanisms of various chemical and biological processes.
Used in Deuterium Production:
Sodium deuteride can be used as a source of deuterium, which is an important isotope for various applications, including nuclear fusion and heavy water production. The compound's high isotopic purity makes it a suitable choice for these purposes.

Check Digit Verification of cas no

The CAS Registry Mumber 15780-28-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,7,8 and 0 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 15780-28:
(7*1)+(6*5)+(5*7)+(4*8)+(3*0)+(2*2)+(1*8)=116
116 % 10 = 6
So 15780-28-6 is a valid CAS Registry Number.
InChI:InChI=1/Na.H/q+1;-1

15780-28-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name sodium deuteride

1.2 Other means of identification

Product number -
Other names SODIUM HYDRIDE {609.1.6}

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:15780-28-6 SDS

15780-28-6Synthetic route

sodium
7440-23-5

sodium

deuterium hydride

deuterium hydride

A

sodium hydride
7646-69-7

sodium hydride

B

sodium deuteride
15780-28-6

sodium deuteride

Conditions
ConditionsYield
In neat (no solvent) byproducts: D, H; Na, HD (10 Torr) heated resistively in a stainless steel "cross" oven to 570 K; not isolated, detected by fluorescence spectroscopy;
sodium
7440-23-5

sodium

deuterium
16873-17-9

deuterium

sodium deuteride
15780-28-6

sodium deuteride

Conditions
ConditionsYield
In further solvent(s) in a satd. hydrocarbon (decane) at 240°C in an autoclave, D2-pressure at begin: 28 atm;;
In neat (no solvent) byproducts: D; Na, HD (1o Torr) heated resistively in a stainless steel "cross" oven to 570 K; not isolated, detected by fluorescence spectroscopy;
In neat (no solvent) on treatment of heated Na with circulating D2 (by reduction of D2O with Fe), 800-810Torr, up to 360°C;;
sodium hydride
7646-69-7

sodium hydride

deuterium
16873-17-9

deuterium

sodium deuteride
15780-28-6

sodium deuteride

Conditions
ConditionsYield
deuterium uptake of NaH at 250°C; detn. by TG;
sodium deuteride
15780-28-6

sodium deuteride

{1,1'-(3-oxa-pentamethylene)dicyclopentadienyl}lutetium chloride

{1,1'-(3-oxa-pentamethylene)dicyclopentadienyl}lutetium chloride

(1,1'-(3-oxa-pentamethylene)dicyclopentadienyl lutetium deuteride)2

(1,1'-(3-oxa-pentamethylene)dicyclopentadienyl lutetium deuteride)2

Conditions
ConditionsYield
In tetrahydrofuran (under Ar), a Schlenk flask is charged with Lu-compd., NaD and THF, mixt. is stirred for 7 days at 45°C; centrifugation, concn., diffusion of pentane at 0°C, washing with pentane, drying in vac., elem. anal.;80.1%
sodium deuteride
15780-28-6

sodium deuteride

{1,1'-(3-oxa-pentamethylene)dicyclopentadienyl}yttrium chloride

{1,1'-(3-oxa-pentamethylene)dicyclopentadienyl}yttrium chloride

(1,1'-(3-oxa-pentamethylene)dicyclopentadienyl yttrium deuteride)2

(1,1'-(3-oxa-pentamethylene)dicyclopentadienyl yttrium deuteride)2

Conditions
ConditionsYield
In tetrahydrofuran (under Ar), a Schlenk flask is charged with Y-compd., NaD and THF, mixt. is stirred for 7 days at 45°C; centrifugation, concn., diffusion of pentane at 0°C, washing with pentane, drying in vac., elem. anal.;68.3%
sodium deuteride
15780-28-6

sodium deuteride

water
7732-18-5

water

A

deuterium hydride

deuterium hydride

B

sodium hydroxide
1310-73-2

sodium hydroxide

Conditions
ConditionsYield
In neat (no solvent) exothermic react., react.-enthalpy given;;

15780-28-6Downstream Products

15780-28-6Relevant articles and documents

Nascent rotational quantum state distribution of NaH (NaD) from the reaction of Na*(42P) with H2, D2, and HD

Bililign, Solomon,Kleiber, P. D.

, p. 213 - 217 (1992)

The nascent rotational quantum state distributions of NaH and NaD products resulting from the reactions of Na*(42Pj) with H2, D2, and HD have been determined using the laser pump-probe technique.We have observed a bimodal rotational distribution with a minor component peaking at low J and a major component peaking at high J.We have observed no evidence for a kinematic isotope effect on the product distribution.Our results are consisent with a model wherein the reaction occurs predominantly on the attractive 2B2 potential energy surface in near C2v geometry with the rotational distribution being determined late in the exit channel.

Hydrogen diffusion in NaH as derived from isotope exchange experiments

Borgschulte,Pendolino,Gremaud,Zuettel

, (2009)

We report on hydrogen-deuterium-exchange experiments on NaH probed by thermogravimetry. From the measurements a diffusion parameter of deuterium in NaH of D=1.1× 10-17 m2 /s at 523 K is derived. The activation energy of tracer diffus

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