157826-51-2

Basic information

• Product Name: methyl 3-bromo-<(E)-3,7-dimethyl-2,6-octadienyl>-4,6-dimethoxy-2-methylbenzoate
• CAS NO: 157826-51-2
• Molecular Weight: 425.363
• Mol File: 157826-51-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 3-bromo-<(E)-3,7-dimethyl-2,6-octadienyl>-4,6-dimethoxy-2-methylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-bromo-<(E)-3,7-dimethyl-2,6-octadienyl>-4,6-dimethoxy-2-methylbenzoate(157826-51-2)
• EPA Substance Registry System: methyl 3-bromo-<(E)-3,7-dimethyl-2,6-octadienyl>-4,6-dimethoxy-2-methylbenzoate(157826-51-2)

Safety Data

• Hazardous Substances Data: 157826-51-2(Hazardous Substances Data)

Upstream product

• 715-33-3 methyl 2,4-dihydroxy-3,5-dibromo-6-methylbenzoate 
• 6138-90-5 trans-geranyl bromide 
• 150965-73-4 methyl 3,5-dibromo-2,4-dimethoxy-6-methylbenzoate 

Relevant articles and documents

A general approach for the synthesis of phenolic natural products. Facile syntheses of grifolin and colletochlorins B and D

A general approach is established for the synthesis of phenolic compounds having terpenoid side chains: (1) protection of the phenolic hydroxyls in the aromatic precursor by ether formation, (2) coupling the aromatic part with a terpenoid bromide, and (3) deprotection to regenerate the hydroxyl groups. This strategy was successfully applied to the synthesis of colletochlorins B and D and grifolin. Some of the colletochlorin derivatives were found to inhibit the cell growth of P388.