157868-96-7Relevant articles and documents
Richter cyclization and co-cyclization reactions of triazene-masked diazonium ions
Goeminne, Annelies,Scammells, Peter J.,Devine, Shane M.,Flynn, Bernard L.
, p. 6882 - 6885 (2011/03/18)
The conventional Richter cyclization involves diazotization of 2-alkynylanilines with HX (aq) (X = Br or Cl) and NaNO2, followed by spontaneous ring closure to give a mixture of 4-halocinnoline and 4-cinnolinone products. The different products
Cinnolines and Pyrazolopyridazines. - Novel Synthetic and Mechanistic Aspects of the Richter Reaction
Vasilevsky, Sergei F.,Tretyakov, Eugene V.
, p. 775 - 780 (2007/10/02)
The thermal cyclization of 2-alkynylbenzenediazonium salts 2 known as the Richter reaction and leading, as described in the literature, only to 4-hydroxycinnolines 6 has been studied.A new probable route to these compounds involving intermediate formation