157994-11-1Relevant articles and documents
Iron-Catalyzed Decarboxylative Olefination of Unstrained Carbon-Carbon Bonds Relying on Alkoxyl Radical Induced Cascade
Gao, Pin,Wu, Hao,Yang, Jun-Cheng,Guo, Li-Na
, p. 7104 - 7108 (2019/09/30)
An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group
Kinetic Resolution of Chiral Hydroperoxides via Sharpless Epoxidation
Hoeft, E.,Hamann, H.-J.,Kunath, A.
, p. 534 - 537 (2007/10/02)
The kinetic resolution of tertiary hydroperoxides via catalytic Sharpless epoxidation with various allylic alcohols has been investigated.By using 1-cyclohexyl-1-phenylethyl hydroperoxide an enantiomeric excess (e.e.) of up to 29percent of the resolved hy